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填料与助熔剂对类陶瓷化聚烯烃炭层的影响研究

艾梁辉 付晓 陈延安 叶南飚

合成材料老化与应用2023,Vol.52Issue(6):12-15,4.
合成材料老化与应用2023,Vol.52Issue(6):12-15,4.

填料与助熔剂对类陶瓷化聚烯烃炭层的影响研究

Study on Effect of Fillers and Fluxes on the Ceramic Polyolefin Char Layer

艾梁辉 1付晓 1陈延安 1叶南飚1

作者信息

  • 1. 金发科技股份有限公司,塑料改性与加工国家工程实验室,广东广州5 10663
  • 折叠

摘要

Abstract

This article investigated the influence of the structure of ceramic fillers and the melting point of fluxes on the ceramic polyolefins char layer.The vertical combustion results indicate that the laminated mica has the strongest carbon formation,and the char layer breaks after 114s,with a fracture length of 10cm;The spherical calcium carbonate carbon layer is the worst,starting to fracture at 93s,with a fracture length of 4cm.When needle like wollastonite is also used as the ceramic filler,when the melting point of glass powder is higher,the char layer can be maintained to fracture for 178s,and the fracture length can reach 15cm.The Leica microscope results of the char layer indicate that the layered ceramic filler forms more dense and complete carbon;The char layer of spherical fillers is loose,fragile,and cracked.When the melting point of glass powder is higher,the density of the char layer is enhanced.We studyed the carbonization mechanism of different ceramic fillers and fluxes through scanning electron microscopy(SEM);The char layers formed by layered fillers are stacked layer by layer,which has a stronger barrier effect;The carbonization of high melting point glass powder is smoother.

关键词

类陶瓷化聚烯烃/炭层/成瓷填料/助熔剂/完整连续

Key words

ceramic polyolefin/char layer/ceramic filler/fluxes/continuity

分类

化学工程

引用本文复制引用

艾梁辉,付晓,陈延安,叶南飚..填料与助熔剂对类陶瓷化聚烯烃炭层的影响研究[J].合成材料老化与应用,2023,52(6):12-15,4.

合成材料老化与应用

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1671-5381

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