核化学与放射化学2023，Vol.45Issue(6)：499-523,25.DOI:10.7538/hhx.2023.45.06.0499
硼烷化合物的合成:从小硼烷分子到多面体硼烷
Synthesis of Borane Complexes:From Small Borane Molecules to Polyhedral Boranes
摘要
Abstract
Borane is a class of boron compounds,including active small borane molecules and relative stable polyhedral borane compounds,and has widely applied in energy storage,material science,and pharmaceutical medicine,especially as promising boron carriers for boron neutron capture therapy(BNCT),and many other fields.The synthesis of new borane molecules and optimization of the synthetic methods of boranes have been a significant part of boron chemistry over the last one hundred years.Herein,we have systematically summa-rized the syntheses of small borane molecules,polyhedral boranes,and carboranes;we also provided the molecular structures and 11B NMR spectra of borane compounds.Anticipated-ly,this review will provide the basic knowledge for readers interested in borane chemistry and facilitate the readers for improving the synthetic methods of boranes and exploring the application of borane compounds.关键词
硼烷/多面体硼烷/硼氢化合物/硼烷合成/硼烷结构Key words
borane/polyhedral borane/borohydride/synthesis of borane/structure of borane分类
核科学引用本文复制引用
荆怡,王盈盈,王凯,郗碧莹,陈学年..硼烷化合物的合成:从小硼烷分子到多面体硼烷[J].核化学与放射化学,2023,45(6):499-523,25.基金项目
国家自然科学基金项目(22171246,U1840253) （22171246,U1840253）
