井冈山大学学报（自然科学版）2023，Vol.44Issue(6)：29-45,17.DOI:10.3969/j.issn.1674-8085.2023.06.005
金属超分子聚合物:复杂拓扑的构筑与力学性能的增强
METALLO-SUPRAMOLECULAR POLYMERS:THE CONSTRUCTION OF SOPHISTICATED TOPOLOGICAL STRUCTURES AND IMPROVEMENT OF MECHANICAL PERFORMANCE
摘要
Abstract
Due to the dynamic and reversible noncovalent interactions,supramolecular polymers exhibit various unique dynamic properties,including self-healing ability,stimuli-responsiveness and mechanical adaptability,and thus show great potentials in the design and preparation of smart materials.As one of typical noncovalent interactions,metal coordination has been widely used in the construction of polymer materials,and a significant concept of metallo-supramolecular polymers(MSPs)has been developed.Compared with other supramolecular interactions,metal coordination has the unique advantages of predictable assembly structures and higher bonding strength,which are important for the accurate construction of topological polymers and effective improvement of mechanical properties.As a result,this review has a detail discussion about the significant progress of MSPs in the construction of polymer topology and the regulation of mechanical properties.Moreover,an outlook is then given to highlight the future opportunities and challenges in the development of MSPs based on the existing research foundation.关键词
超分子聚合物/金属配位作用/拓扑结构/力学性能Key words
supramolecular polymer/metal coordination/topological structure/mechanical performance分类
化学化工引用本文复制引用
刘昱迒,郭钰郴,颜徐州..金属超分子聚合物:复杂拓扑的构筑与力学性能的增强[J].井冈山大学学报（自然科学版）,2023,44(6):29-45,17.基金项目
国家自然科学基金项目(22122105,22071152) （22122105,22071152）
上海市自然科学基金项目(20ZR1429200,22dz1207603) （20ZR1429200,22dz1207603）
