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不同配比和粒度下黄铁矿和石灰石静态浸泡试验

李海伟 宋红娜 李利娟 廖佳佳 武成周 夏大平

净水技术2023,Vol.42Issue(12):110-118,9.
净水技术2023,Vol.42Issue(12):110-118,9.DOI:10.15890/j.cnki.jsjs.2023.12.014

不同配比和粒度下黄铁矿和石灰石静态浸泡试验

Static Soaking Test of Pyrite and Limestone at Different Proportions and Particle Sizes

李海伟 1宋红娜 2李利娟 1廖佳佳 3武成周 1夏大平4

作者信息

  • 1. 河南省资源环境调查三院,河南郑州 450000
  • 2. 河南理工大学工商管理学院,河南焦作 454003
  • 3. 河南理工大学资源环境学院,河南焦作 454003
  • 4. 河南理工大学资源环境学院,河南焦作 454003||煤炭安全生产与清洁高效利用省部共建协同创新中心,河南焦作 454000||河南理工大学矿业研究院,河南焦作 454003
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摘要

Abstract

In order to make further investigation for the characteristics and patterns of acidogenicity of pyrite in the Gongyi mining area,and to study the best solution for the treatment of acid mine water by neutralisation method in the area,a mixed leaching experiment was conducted with three grain sizes of pyrite and different proportions of limestone respectively,and the changes in pH,TDS,Con and anion concentration of the leaching solution were analyzed,as well as the changes in mineral composition and pore reference of the rock samples before and after the reaction.Results showed that:(1)Large amounts of SO2-4 could be generated from the leaching of pyrite in the Gongyi mine,and its value in the leaching solution exceeded the class Ⅲ groundwater standard.(2)The higher the proportion of pyrite,the lower the pH of the soaking solution,the higher the concentration of precipitated anions and cations,and the greater the changes in specific surface area and porosity;and the acidity of the soaking solution gradually decreased with the extension of the soaking time,indicating that the neutralizing effect of limestone was slowly exerted,and the addition of 25%~50%limestone could neutralize acidic water.

关键词

黄铁矿/石灰石/静态浸泡试验/溶出规律/酸性矿井水

Key words

pyrite/limestone/static soaking test/dissolution rule/acidic mine water

分类

资源环境

引用本文复制引用

李海伟,宋红娜,李利娟,廖佳佳,武成周,夏大平..不同配比和粒度下黄铁矿和石灰石静态浸泡试验[J].净水技术,2023,42(12):110-118,9.

基金项目

国家自然科学基金资助项目(42172199) (42172199)

教育部博士点基金(200804600001) (200804600001)

河南省优秀青年科学基金资助项目(202300410168) (202300410168)

河南理工大学博士基金(SKB2022-12) (SKB2022-12)

净水技术

OACSTPCD

1009-0177

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