林产化学与工业2023，Vol.43Issue(6)：25-32,8.DOI:10.3969/j.issn.0253-2417.2023.06.004
大豆油基木器涂料的合成及其阻燃性能研究
Synthesis and Properties of Soybean Oil-based Flame Retardant Wood Coatings
摘要
Abstract
Hydrophobic nano-SiO2 modified bio-based UV curable resin was prepared using glycidyl methacrylate modified itaconic acid prepolymer(GI)and epoxy soybean oil(ESO)based synthetic product GIESO as raw materials and using tetrahydrofuran methacrylate(THFMA)as diluent.Then,9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide(DOPO)as a phosphorus-containing flame retardant was introduced to prepare a UV-curable wood coatings with hydrophobic and flame retardant properties.The effects of SiO2 and DOPO on coating properties were studied by adjusting the relative contents of these two components in the resins.The research results showed that when the amount of SiO2 was0.5%(calculated by the mass of GIESO/THFMA,which was also applied as below),the comprehensive performance of the coating GIESO/THFMA-Si0.5 was the best,with a water absorption rate of 0.49%and a contact angle of 108.2°.When the dosage of DOPO was20%,a UV-curable wood coatings with high film coating,hydrophobic and flame retardant properties was prepared.The hardness of film was 6H,the adhesion was level 1,the flexibility was4 mm,the contact angle was103.7° and the limiting oxygen index(LOI)was up to24.0%.关键词
木器涂料/紫外光固化/疏水/阻燃Key words
wood coating/UV-curing/hydrophobic/flame retardancy分类
化学化工引用本文复制引用
张飞,马越,黄佳,胡云,刘承果,周永红..大豆油基木器涂料的合成及其阻燃性能研究[J].林产化学与工业,2023,43(6):25-32,8.基金项目
公安部重点实验室开放基金资助项目(HJKF201905) （HJKF201905）
中国林科院中央级公益性科研院所基本科研业务费专项资金(CAFYBB2020QA005) （CAFYBB2020QA005）
