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Fe(Ⅱ)(Ⅲ)—EDTA体系研究(Ⅳ)

赵梦月 吕灵翠 李随聚 张松

郑州大学学报(工学版)1988,Vol.9Issue(4):15-20,6.
郑州大学学报(工学版)1988,Vol.9Issue(4):15-20,6.

Fe(Ⅱ)(Ⅲ)—EDTA体系研究(Ⅳ)

Study of The Fe(Ⅱ)(Ⅲ)—Edta System(Ⅳ)

赵梦月 1吕灵翠 1李随聚 1张松1

作者信息

  • 1. 郑州工学院化工系
  • 折叠

摘要

Abstract

This paper deals with the rule of photoreduction of system of Fe(Ⅱ)(Ⅲ)—phen in process of extraction. It is discovered that in diffused light a remarable photoreduction of Fe3+—phen complex occurs;that when EDTA is added into the system the photoreduetion is prevented,however thereaction in which Fe(Ⅲ)is reduced into Fe(Ⅱ)by NH2OH.HCl is not in-fluenced;and that the determination of iron valence state is not affected when a small amount of reduet(S2O32-)is present. This method can be applied to the determination of Fevaleuce state in system of Fe(Ⅱ)(Ⅲ)—EDTA.

关键词

邻菲啰啉光度法/光还原

Key words

phen spectrophotometry/photoreduction

引用本文复制引用

赵梦月,吕灵翠,李随聚,张松..Fe(Ⅱ)(Ⅲ)—EDTA体系研究(Ⅳ)[J].郑州大学学报(工学版),1988,9(4):15-20,6.

郑州大学学报(工学版)

1671-6833

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