大学化学2023，Vol.38Issue(11)：126-130,5.DOI:10.3866/PKU.DXHX202304025
全氟立方烷的笼状立体电子效应
Cage-Type Stereoelectronic Effects of Perfluorocubane
摘要
Abstract
As an essential component of fundamental organic chemistry theory,stereoelectronic effects,including the common gauche and anomeric effects,have been intensively investigated and discussed in undergraduate courses.Nevertheless,with the precise prediction and successful synthesis of perfluorocubane,a new cage-type stereoelectronic effect has attracted considerable attention from chemists.Herein,we briefly review the development of stereoelectronic effects,including their wide-ranging applications in organic chemistry.In particular,we highlight recent investigations on perfluorocubane synthesis and discuss the interesting cage-type stereoelectronic effects.The positive interplay between the scientific frontiers and the organic chemistry course will significantly influence the global perspective of students by expanding their knowledge of organic chemistry,and the fundamental concepts and advanced applications of stereoelectronic effects.关键词
立体电子效应/有机合成/全氟立方烷Key words
Stereoelectronic effects/Organic synthesis/Perfluorocubane分类
社会科学引用本文复制引用
李懿伦,袁耀锋,叶克印..全氟立方烷的笼状立体电子效应[J].大学化学,2023,38(11):126-130,5.基金项目
福州大学一流学科本科教学改革建设项目:中国高等教育学会2021年度理科专项课题(21LKYB07) （21LKYB07）
教育部2022年度基础学科拔尖计划2.0研究课题(20222114) （20222114）
