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Al0.25Li6.25La3Zr2O12包覆LiCoO2降低锂离子电池界面阻抗

赵来安

福建冶金2024,Vol.53Issue(1):58-61,4.
福建冶金2024,Vol.53Issue(1):58-61,4.

Al0.25Li6.25La3Zr2O12包覆LiCoO2降低锂离子电池界面阻抗

Al0.25Li6.25La3Zr2O12 Coated LiCoO2 Reduces Interface Impedance for Lithium-ion Battery

赵来安1

作者信息

  • 1. 厦门厦钨新能源材料股份有限公司,福建厦门 361026
  • 折叠

摘要

Abstract

In this thesis,Al0.25Li6.25La3Zr2O12(LLZO)-coated LiCoO2(LCO)materials were prepared by solid-phase sintering to improve interface stability and reduce interface impedance.The experimental results show that the electrochemical performance is significantly improved.When charged and discharged for 50 cycles in the voltage range of 3.0-4.62 V,the specific capacity retention rate of the coated material is 70%,which is higher than 65%of the uncoated material.In addition,the charge transfer resistance of the coated material was reduced from 22.5 Ω to 15.0 Ω,rate performance was improved.The effect of solid electrolyte LLZO coated lithium cobalt on electrical properties was studied in this work,and has great reference significance for the design of fast charge lithium cobalt oxide battery material.

关键词

锂离子电池/钴酸锂/Al0.25Li6.25La3Zr2O12/包覆

Key words

lithium-ion battery/LiCoO2/Al0.25Li6.25La3Zr2O12/coated

引用本文复制引用

赵来安..Al0.25Li6.25La3Zr2O12包覆LiCoO2降低锂离子电池界面阻抗[J].福建冶金,2024,53(1):58-61,4.

福建冶金

1672-7665

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