广州化学2023，Vol.48Issue(6)：1-7,7.DOI:10.16560/j.cnki.gzhx.20230619
动态亚胺化学的分子设计及其动态性质研究
Study on Molecular Design and Dynamic Properties of Dynamic Imide Chemistry
摘要
Abstract
Several imine small molecule monomers were successfully prepared by molecular design.The three kinds of dynamic reaction mechanism of imine small molecule model compounds were investigated by using online nuclear magnetic hydrogen spectroscopy and GC-MS analysis.The results show that when two different imine small molecule model compounds are mixed,the metathesis reaction between imine bonds can occur without catalyst.Secondly,when there is another primary amine compound in the system,the imine bond can be aminotransfered.In addition,in acidic aqueous solution,the imine bond is easily hydrolyzed and hydrolyzed into small molecular monomers containing aldehyde and amino groups.关键词
动态共价键/亚胺键/复分解反应/转氨反应/水解反应Key words
dynamic covalent bond/imine bond/metathesis reaction/transamination reaction/hydrolysis reaction分类
化学引用本文复制引用
刘小红,刘家铭,秦静静,梁利岩..动态亚胺化学的分子设计及其动态性质研究[J].广州化学,2023,48(6):1-7,7.基金项目
广东省科技专项资金项目(项目编号210906134536798) （项目编号210906134536798）
