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Al-LiH复合燃料制备及性能OACSTPCD

Preparation and Performance of Al-LiH Composite Fuel

中文摘要英文摘要

为了提高铝粉燃烧效率,利用球磨法分别制备了质量含量为3%,5%,10%,15%的Al-LiH复合燃料.通过X射线衍射仪(XRD)、扫描电镜(SEM)、粒度仪对样品结构、形貌和粒径进行表征;采用差热-热重量热仪对其热氧化性能进行表征,最后采用CO2激光点火装置、高速摄像机及氧弹量热仪对其燃烧性能进行考察.结果表明:通过球磨法可以将LiH嵌入Al粉内部,LiH含量是影响其微观形貌及粒径、粒径分布的关键因素,LiH的加入使得燃料质量热值增加,同时随着LiH含量的增加Al-LiH复合燃料燃烧火焰强度增强,点火延迟时间大幅降低.其中由于Al-LiH复合燃料在高温下发生了微爆现象,Al-3LiH和Al-10LiH复合燃料在一次氧化后分别实现第二次氧化.

To improve the combustion efficiency of aluminum powders,Al-LiH composite fuels with mass contents of 3%,5%,10%,and 15%were prepared using the ball milling method,respectively.The sample structure,morphology,and particle size are characterized by X-ray diffraction(XRD),scanning electron microscopy(SEM),and particle size analyzer.The thermal oxi-dation performance was characterized using the DSC-TG.Finally,their combustion performance was investigated using the CO2 laser ignition device,high-speed camera,and oxygen bomb calorimeter.The results show that LiH can be embedded into Al powder through the ball milling method,and the LiH content is a key factor affecting its microstructure,particle size,and parti-cle size distribution.The addition of LiH increases the mass calorific value of fuel.At the same time,with the increase of LiH con-tent,the combustion flame intensity of Al-LiH composite fuel increases and the ignition delay time significantly decreases.Among them,Al-3LiH and Al-10LiH composite fuels achieve second oxidation after the first oxidation.The analysis suggests that the second oxidation phenomenon is caused by the microexplosion phenomenon of Al-LiH composite fuel at high temperatures.

王芳;张鑫鹏;王鼎程;李春涛;孙鑫科;冯勇;李伟

航天化学动力技术重点实验室,湖北 襄阳 441003||湖北航天化学技术研究所,湖北 襄阳 441003湖北航天化学技术研究所,湖北 襄阳 441003

武器工业

铝粉氢化锂推进剂燃烧性能

aluminum powderlithium hydridepropellantcombustion performance

《含能材料》 2024 (001)

微爆型Al-LiH复合燃料制备及燃烧模型构建

12-19 / 8

国家自然科学基金(22105067,22375058) National Nature Science Foundation of China(Nos.22105067,22375058)

10.11943/CJEM2023197

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