化工环保2023，Vol.43Issue(6)：780-787,8.DOI:10.3969/j.issn.1006-1878.2023.06.010
SrxCoO3钙钛矿活化过硫酸盐降解罗丹明B
Degradation of Rhodamine B by persulfate activated with SrxCoO3 perovskite
摘要
Abstract
The SrxCoO3 catalyst was synthesized by sol-gel method and characterized by XRD and SEM.The degradation effect of Rhodamine B(RhB)in solution by SrxCoO3 activated peroxydisulfate(PMS)was examined.The characterization results reveal a perovskite-like crystal structure of the SrxCoO3 catalyst.The experimental results show that under the conditions of pH 3.0-9.0,Sr0.8CoO3 amount 0.030 g/L,PMS amount 0.06 mmol/L and reaction time 30 min,the RhB removal rate can reach 96％.The response surface analysis results indicate that there is a synergistic effect among the initial pH,Sr0.8CoO3 amount and PMS amount,and the effect of Sr0.8CoO3 amount and PMS amount is more significant.The predicted values from the regression model established using Design-Expeter software are highly correlated with the experimental values,accurately reflecting the actual removal of RhB.关键词
锶钴基钙钛矿/过一硫酸盐/响应曲面/罗丹明BKey words
strontium cobalt-based perovskite/peroxomonosulfate/response surface/Rhodamine B分类
资源环境引用本文复制引用
殷喜平,苑志伟,任靖,韩帅,赵保槐,李柯志..SrxCoO3钙钛矿活化过硫酸盐降解罗丹明B[J].化工环保,2023,43(6):780-787,8.基金项目
中国石化催化剂有限公司科学技术研究开发项目(SCC-B-2023-027). （SCC-B-2023-027）
