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自抛光防污涂层的水渗透特性及其对抛光速率的影响研究

张焕娟 丛巍巍 张凯 苏荣国 桂泰江

中国海洋大学学报(自然科学版)2024,Vol.54Issue(2):99-105,7.
中国海洋大学学报(自然科学版)2024,Vol.54Issue(2):99-105,7.DOI:10.16441/j.cnki.hdxb.20220490

自抛光防污涂层的水渗透特性及其对抛光速率的影响研究

Study on Water Penetration Characteristics of Self-Polishing Antifouling Coatings and Their Effect on Polishing Rates

张焕娟 1丛巍巍 2张凯 2苏荣国 3桂泰江2

作者信息

  • 1. 中国海洋大学化学化工学院,山东 青岛 266100||海洋化工研究院有限公司,海洋涂料国家重点实验室,山东 青岛 266071
  • 2. 海洋化工研究院有限公司,海洋涂料国家重点实验室,山东 青岛 266071
  • 3. 中国海洋大学化学化工学院,山东 青岛 266100
  • 折叠

摘要

Abstract

Antifouling coatings applied to the surface of marine facilities can significantly cut down on the economic losses caused by biofouling.Among them,self-polishing antifouling coatings have become the leading products in the antifouling coatings market for their good polishing performance and excel-lent antifouling effect.The permeation behavior of water in two acrylic silicone self-polishing antifouling coatings A1 and A2 was analyzed and compared by electrochemical impedance spectroscopy(EIS),and the polishing rates of the two coatings in 3.5%artificial seawater were measured by dynamic simulation tests.The EIS results demonstrated that the water penetration in both acrylic silicone self-polishing an-tifouling coatings followed the Fick diffusion pattern,which were then fitted to give a saturated volume percentage of water absorption approximately 11.5%for coating A1 and 20%for coating A2.According to dynamic simulations,the polishing rates in 3.5%artificial seawater was 0.15 μm/d for antifouling coat-ing A1 and 0.26 μm/d for coating A2.The higher saturated volume percentage of water absorption has a more favorable effect on the ability to hydrolyze of the silicone acrylate resin,which speeds up polishing.

关键词

自抛光防污涂层/电化学阻抗谱/水渗透/抛光速率

Key words

self-polishing antifouling coatings/electrochemical impedance spectroscopy/water perme-ability/polishing rate

分类

化学工程

引用本文复制引用

张焕娟,丛巍巍,张凯,苏荣国,桂泰江..自抛光防污涂层的水渗透特性及其对抛光速率的影响研究[J].中国海洋大学学报(自然科学版),2024,54(2):99-105,7.

基金项目

国家自然科学基金委员会-山东省人民政府联合基金项目(U2006219) (U2006219)

国防基础科研计划项目(JCKY2021513B001)资助Supported by the Joint Fund of the National Natural Science Foundation of China and the Shandong Provincial People's Government(U2006219) (JCKY2021513B001)

the Defense Industrial Technology Development Program(JCKY2021513B001) (JCKY2021513B001)

中国海洋大学学报(自然科学版)

OACSTPCD

1672-5174

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