中国造纸学报2023，Vol.38Issue(4)：41-47,7.DOI:10.11981/j.issn.1000-6842.2023.04.41
磁性固相萃取结合气质联用仪检测造纸废水中的氯酚类化合物
Magnetic Solid-phase Extraction Combined with GC-MS for Chlorophenols Analysis in Papermaking Waste water
摘要
Abstract
In this study,magnetic polystyrene(Fe3O4@PS)microspheres were used as adsorbents in solid phase extraction combined with GC-MS to evaluate the efficiency of extracting chlorophenols(CPs)from papermaking wastewater.The novel microspheres were character-ized by transmission electron microscope(TEM),X-ray diffraction(XRD)and fourier-transform infrared spectroscopy(FT-IR).The main influence parameters of the magnetic solid-phase extraction(MSPE),such as the amount of sorbent,extraction time and elution condition,were investigated and optimized.The results demonstrated that 20 mg of sorbent,7 min of desorption time and 2 mL of eluent solvent were chosen as the optimum conditions.Under the optimum conditions,an excellent linearity was observed in the range of 2.5～2000 μg/L.The LODs for chlorophenols were in the range of 0.076～0.207 μg/L and the correlation coefficients ranging from 0.9966～0.9994.The proposed method was successfully applied for the analysis of papermaking wastewater samples with recoveries ranging from 83.39％～109.40％.The above results demonstrated that Fe3O4@PS as a MSPE absorbent performed effective extraction efficiency and simplified operation process in the trace analysis of CPs.关键词
磁性聚苯乙烯微球/气质联用/造纸废水/氯酚Key words
Fe3O4@PS/GC-MS/papermaking wastewater/chlorophenols分类
资源环境引用本文复制引用
董云渊,王滢,史君齐,岳跃振,骆华英,郑启富,张敏,廖建明,陈晓彬..磁性固相萃取结合气质联用仪检测造纸废水中的氯酚类化合物[J].中国造纸学报,2023,38(4):41-47,7.基金项目
衢州市科技计划项目(2023K230、2018K38) （2023K230、2018K38）
浙江省基础公益计划项目(LGN21C030001) （LGN21C030001）
浙江大学衢州研究院科技计划项目(IZQ2019-KJ-028) （IZQ2019-KJ-028）
衢州市重点研发计划项目(2021Z01) （2021Z01）
衢江区科技计划项目(QJ2019J001、QJ2020012、QJ2020022、QJ2021038,QJ2021040). （QJ2019J001、QJ2020012、QJ2020022、QJ2021038,QJ2021040）
