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N与F共掺杂空心碳球用于电催化合成H2O2的试验研究

朱伟俊 蔡业钊

中国资源综合利用2023,Vol.41Issue(12):28-30,3.
中国资源综合利用2023,Vol.41Issue(12):28-30,3.DOI:10.3969/j.issn.1008-9500.2023.12.008

N与F共掺杂空心碳球用于电催化合成H2O2的试验研究

Experimental Study on N and F Codoped Hollow Carbon Spheres for Electrocatalytic Synthesis of H2O2

朱伟俊 1蔡业钊1

作者信息

  • 1. 珠海市清创智慧海绵技术研究院有限公司,广东 珠海 519080
  • 折叠

摘要

Abstract

The dual electron(2e-)oxygen reduction reaction(ORR)can be used for electrocatalytic synthesis of H2O2,which is a green technology that can continuously synthesize H2O2,however,developing catalysts with high activity and selectivity remains a major challenge.The experiment prepares a heteroatom doped porous hollow carbon catalyst(FNCS)by carbonizing carbon spheres(CS)and ammonium fluoride(NH4F),which not only achieves dual doping of N and F,but also makes the carbon spheres have a cavity structure.The results indicate that FNCS exhibits excellent dual electron oxygen reduction reaction performance,with a wide potential range of 0.3~0.5 V and a selectivity of up to 60%for H2O2,it has great potential for application in the field of H2O2 synthesis.

关键词

电催化/H2O2/氧还原反应/催化剂

Key words

electrocatalysis/H2O2/oxygen reduction reaction/catalyst

分类

化学化工

引用本文复制引用

朱伟俊,蔡业钊..N与F共掺杂空心碳球用于电催化合成H2O2的试验研究[J].中国资源综合利用,2023,41(12):28-30,3.

中国资源综合利用

OACHSSCD

1008-9500

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