大学化学2023,Vol.38Issue(12):165-180,16.DOI:10.3866/PKU.DXHX202305034
不对称C-H/C-H交叉脱氢偶联反应研究进展
Research Progress of Asymmetric C-H/C-H Cross Dehydrogenation Coupling Reaction
摘要
Abstract
In recent years,the cross-dehydrogenative coupling(CDC)reaction has received widespread attention in the field of organic synthetic chemistry.This strategy avoids the pre-functionalization of substrates in the reactions that form carbon-carbon bonds.It demonstrates high atomic economy and aligns with the development requirements of green chemistry.Furthermore,asymmetric CDC reactions can realize stereoselective construction of carbon-carbon bonds,which currently constitutes a key area of research in organic synthesis.This paper reviews the research progress in asymmetric CDC reactions and provides a perspective on the future development direction in this field.关键词
不对称催化/绿色化学/碳-氢键活化/碳-碳键构筑/研究进展Key words
Asymmetric catalysis/Green chemistry/C-H activation/C-C bond formation/Research progress分类
社会科学引用本文复制引用
李天宇,吴丹清,刘佳俊,徐大振,苗志伟..不对称C-H/C-H交叉脱氢偶联反应研究进展[J].大学化学,2023,38(12):165-180,16.基金项目
国家自然科学基金面上项目(22071113) (22071113)
福建省南平市科技项目(N2020Z008) (N2020Z008)