氮化硅陶瓷低温烧结助剂研究进展OA
Research progress of low temperature sintering additives forsilicon nitride ceramics
氮化硅陶瓷性能优异,然而由于其共价键较强,自扩散系数小,烧结难度较大.目前高性能氮化硅陶瓷主要通过高温气压烧结法制备,烧结温度在 1 800℃以上,对设备要求较高,制备成本也较高,限制了氮化硅陶瓷的实际应用.低温烧结作为降低氮化硅生产成本的有效途径之一,受到了业界广泛关注.目前国内外关于氮化硅陶瓷低温烧结的研究主要集中在烧结助剂的选择方面,烧结助剂可以分为两类:使用与 SiO2 共晶温度较低的烧结助剂和使用多组分烧结助剂.综述了这两类低温烧结助剂的研究进展,并提出了低温烧结助剂选择的合理方案.综合来看,要在低温下制得性能良好的氮化硅陶瓷,需选用与SiO2 具有低共晶点的烧结助剂,并配合使用多元组分调控氮化硅陶瓷的微观结构和性能.
Silicon nitride ceramics have excellent properties,but because of its strong covalent bond and small self-diffusion coefficient,it is difficult to sintering.At present,high performance silicon nitride ceramics are mainly pre-pared by high-temperature pressure sintering method,sintering temperature is above 1 800℃,which requires high equipment and preparation cost,limiting the practical application of silicon nitride ceramics.As one of the effective ways to reduce the production cost of silicon nitride,low temperature sintering has been widely concerned.At present,the research on the low-temperature sintering of silicon nitride ceramics at home and abroad mainly focuses on the selection of sintering additives,which can be divided into two categories:the use of sintering additives with low eutec-tic temperature of SiO2 and the use of multi-component sintering additives.The research progress of these two kinds of low-temperature sintering auxiliaries is reviewed,and a reasonable scheme for the selection of low-temperature sinte-ring auxiliaries is proposed.In summary,in order to produce silicon nitride ceramics with good performance at low temperatures,it is necessary to choose asintering agent with low eutectic point with SiO2,and use multiple-compo-nents control to regulate the microstructure and properties of silicon nitride ceramics.
周泊岸;唐志红;李哲;张景贤
上海理工大学 材料与化学学院,上海 200093||中国科学院上海硅酸盐研究所高性能陶瓷和超微结构国家重点实验室,上海 200050上海理工大学 材料与化学学院,上海 200093中国科学院上海硅酸盐研究所高性能陶瓷和超微结构国家重点实验室,上海 200050
化学工程
氮化硅低温烧结致密化硅酸盐液相共晶温度多组分烧结助剂
Si3 N4 ceramicslow-temperature sinteringdensificationsilicate liquid phaseeutectic temperaturemulticomponent sintering aid
《化工矿物与加工》 2024 (001)
69-75 / 7
国家重点研发计划项目(2022YFB3706300);国家自然科学基金项目(52102082);上海市青年科技启明星计划项目(21YF1454500).
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