江汉大学学报(自然科学版)2024,Vol.52Issue(1):5-15,11.DOI:10.16389/j.cnki.cn42-1737/n.2024.01.001
一种基于三苯胺-噻吩基团的新型荧光探针在藻细胞中检测CN‒的应用
A Novel Triphenylamine-thiophene Dyad Fluorescent Probe for Cyanide Detection in Living Algae Cells
摘要
Abstract
Cyanide(CN‒)is one of the most well-known toxic anions,some edible algae can release cyanide or absorb cyanide from their living environments,which may cause harm to human health.Therefore,we designed and synthesized a novel fluorescent probe TI for CN‒detection in living algae cells.Probe TI was constructed by triphenylamine-thiophene moiety and indolium moiety and exhibited remarkable blue fluorescence at 473 nm upon treatment with cyanide due to the nucleophilic attack of CN‒ on the C=N bond.Moreover,probe TI demonstrated excellent selectivity and sensitivity(LOD 95.7 nmol/L),and a fast responsive time for cyanide detection in an aqueous solution.Most importantly,probe TI could be applied for real-time detection of CN‒in living algae cells and edible algae.关键词
三苯胺-噻吩/吲哚/CN‒检测/荧光探针/藻细胞Key words
triphenylamine-thiophene/indolium/CN‒detection/fluorescence probe/algae cells分类
化学化工引用本文复制引用
文丹,喻艳华..一种基于三苯胺-噻吩基团的新型荧光探针在藻细胞中检测CN‒的应用[J].江汉大学学报(自然科学版),2024,52(1):5-15,11.基金项目
Jianghan University Science and Technology Special Project(2011KJZX001) (2011KJZX001)