超低压纳滤膜在常规-纳滤工艺深度处理的应用评估OACSTPCD
Application Assessment of Ultra-Low-Pressure NF Membrane in Advanced Treatment by Conventional-NF Process
以太湖流域某水厂砂滤池出水为研究对象,采用两款新型超低压纳滤膜(CDY1、CDY2)分别对其开展深度处理应用研究,重点考察超低压纳滤膜的运行压力、化学清洗恢复情况,及其对有机物、钙镁、总硬度等的去除效果.试验结果表明:超低压纳滤膜对耗氧量、总有机碳、硫酸盐、氨氮去除率,以及对锑、土臭素、2-甲基异莰醇等水质风险控制与常规纳滤膜(国内外主流纳滤膜商品)相当,但前者运行压力低、通量大,且对总硬度、钙等去除效果均低于后者.由于超低压纳滤膜自身的差异,CDY2 对浑浊度、CODMn、TOC、总硬度、钙的去除率均略低于CDY1,但其对硫酸根、锑去除率大于CDY1.此外,化学清洗效果分析结果显示,CDY2 纳滤膜易受胡敏酸相关的腐殖质污染,而CDY1 纳滤膜则易受微生物代谢物+胡敏酸相关的腐殖质+富里酸和胡敏酸污染.
The research object was the sand filter outflow of a water treatment plant in Taihu Basin,and two novel ultra-low-pressure nanofiltration(ULP-NFs)(CDY1 and CDY2)membranes were utilized to advanced treatment of drinking water.The key parameters of the two ULP-NFs were focus on the pressure,properties recovery of chemical cleaning,removal ratio of CODMn,calcium,total harness,et al.The results indicated that the removal ratio of CODMn,TOC,sulfate,ammonia nitrogen,turbidity of CDY1 and CDY2 were equivalent with the conventional nanofiltration membrane(main nanofiltration membrane products from domestic and abroad).Besides,the CDY1 and CDY2 could effectively control the water quality risks such as stibium,geosmin and 2-methylisoborneol.Whereas,the removal ratio of total hardness,calcium by CDY1 and CDY2 were significantly decreased.However,due to the variance between ultra-low pressure nanofiltration membranes,CDY2 showed slightly lower removal ratio of turbidity,CODMn,TOC,total hardness and calcium than those of CDY1,but larger removal ratio of sulfate and stibium.Besides,chemical cleaning effect analysis results showed that CDY2 was easily polluted by humic acid related humus,while CDY1 was susceptible to microbial metabolites + humic acid related humus + fulvic acid and humic acid pollution.
张平允;钱灏;尹松岩;徐鸿凯;俞莉峰
上海城市水资源开发利用国家工程中心有限公司,上海 200082上海城投水务<集团>有限公司,上海 200002
环境科学
超低压纳滤膜饮用水深度处理水质指标
ultra-low-pressure(ULP)NF membranedrinking wateradvanced treatmentwater quality index
《净水技术》 2024 (001)
58-67 / 10
2021年上海市人才发展资金资助计划(2021048)
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