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高熵合金在电催化氧还原反应中的应用及发展

何小波 丁露 银凤翔 李国儒

常州大学学报(自然科学版)2024,Vol.36Issue(1):27-38,12.
常州大学学报(自然科学版)2024,Vol.36Issue(1):27-38,12.DOI:10.3969/j.issn.2095-0411.2024.01.004

高熵合金在电催化氧还原反应中的应用及发展

Applications and developments of high-entropy alloys toward electrocatalytic oxygen reduction reaction

何小波 1丁露 2银凤翔 1李国儒1

作者信息

  • 1. 江苏省绿色催化材料与技术重点实验室(常州大学),江苏常州 213164||常州大学石油化工学院,江苏常州 213164
  • 2. 常州大学石油化工学院,江苏常州 213164
  • 折叠

摘要

Abstract

The development of highly efficient catalysts for oxygen reduction reaction(ORR)is the key to improve the performance of fuel cells and metal-air batteries.However,ORR is a kinetic slow reaction with high overpotential,which limits the energy conversion efficiency of fuel cells and metal-air batteries.High-entropy alloy is a new kind of alloy,which is consisted of five or more metal ele-ments with(nearly)equimolar ratios.With unique composition and structural advantages,high-entro-py alloy can effectively accelerate ORR kinetics and lower overpotential,showing remarkable catalytic performance toward ORR.In this paper,the structures,properties,preparation methods and applications of high entropy alloys in catalytic ORR were reviewed,and the challenges and development perspec-tives were proposed.

关键词

催化剂/电催化/高熵合金/氧还原反应

Key words

catalyst/electrocatalysis/high-entropy alloy/oxygen reduction reaction

分类

化学化工

引用本文复制引用

何小波,丁露,银凤翔,李国儒..高熵合金在电催化氧还原反应中的应用及发展[J].常州大学学报(自然科学版),2024,36(1):27-38,12.

基金项目

国家自然科学基金资助项目(22078027) (22078027)

常州市科技计划应用基础研究计划资助项目(CJ20220253). (CJ20220253)

常州大学学报(自然科学版)

2095-0411

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