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醋酸钾对烟草热解产酚特性的影响

贝书源 武荣成 鹿洪亮 赵大伟 陆鹏飞

生物质化学工程2024,Vol.58Issue(1):41-48,8.
生物质化学工程2024,Vol.58Issue(1):41-48,8.DOI:10.3969/j.issn.1673-5854.2024.01.006

醋酸钾对烟草热解产酚特性的影响

Effect of CH3COOK on the Phenols Production Characteristics of Tobacco Pyrolysis

贝书源 1武荣成 2鹿洪亮 3赵大伟 1陆鹏飞2

作者信息

  • 1. 沈阳化工大学化学工程学院,辽宁沈阳 110142
  • 2. 中国科学院过程工程研究所多相复杂系统国家重点实验室,北京 100190
  • 3. 福建中烟工业有限责任公司技术中心,福建厦门 361021
  • 折叠

摘要

Abstract

In order to investigate the effect of CH3 COOK on the phenols production characteristics of waste tobacco pyrolysis and its influencing factors,the effect of different potassium salts on the generation of typical phenolic compounds from the pyrolysis of waste tobacco was investigated.The effect of CH3 COOK on the phenols production characteristics of biomasses pyrolysis with different protein,cellulose,and lignin contents was also analyzed.The results showed that at a loading amount of 5.00%,compared to the unloaded spent secondary tobacco,CH3COOK could significantly reduce the phenol and catechol percentage and enhance the hydroquinone percentage in the tobacco pyrolysis products.Among them,phenol decreased by 45.63%,catechol decreased by 67.88%,and hydroquinone increased by 32.80%.CH3COOK could decrease the proportion of phenol and catechol in the pyrolysis products of tobacco,mulberry leaf and ginkgo biloba with high protein content,and increase the percentage of phenol,catechol,and guaiacol produced by the pyrolysis of pine chips with low protein and high cellulosic lignin.The significant percentage of phenol,p-cresol,and catechol in the pyrolysis products of tobacco proteins was 19.99%,3.08%,and 2.69%,respectively.After loading CH3COOK,the proportions of phenol andp-cresol in pyrolysis products were reduced by 77.09%and 79.37%,respectively,and no catechol was detected.CH3COOK mainly reduced the percentage of corresponding phenols in tobacco pyrolysis products by inhibiting the pyrolysis of proteins to produce phenol and catechol in tobacco.

关键词

醋酸钾/废次烟草/热解/酚类化合物/蛋白质/主控因素

Key words

potassium acetate/tobacco waste/pyrolysis/phenolic compounds/protein/main control factor

分类

化学化工

引用本文复制引用

贝书源,武荣成,鹿洪亮,赵大伟,陆鹏飞..醋酸钾对烟草热解产酚特性的影响[J].生物质化学工程,2024,58(1):41-48,8.

基金项目

国家自然科学基金资助项目(U1908201) (U1908201)

生物质化学工程

OACSTPCD

1673-5854

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