塑料科技2023,Vol.51Issue(12):11-16,6.DOI:10.15925/j.cnki.issn1005-3360.2023.12.003
EBS和PP-g-MAH对聚丙烯/纳米二氧化钛共混物性能的影响
Effect of EBS and PP-g-MAH on Properties of Polypropylene/Nano-TiO2
郭月圆 1宋立新 2邵文君 1张雨 1刘欣 2刘立志 1史颖1
作者信息
- 1. 沈阳化工大学 高分子产业高端制造研究院,辽宁 沈阳 110142
- 2. 沈阳化工大学 高分子产业高端制造研究院,辽宁 沈阳 110142||沈阳化工大学材料科学与工程学院,辽宁 沈阳 110142
- 折叠
摘要
Abstract
The dispersion of nano-titanium dioxide(TiO2)in polypropylene(PP)is closely related to the mechanical and antibacterial properties of the material.PP,TiO2,N,N'-ethylene bis-stearamide(EBS),and maleic anhydride grafted polypropylene(PP-g-MAH)were blended using a twin-screw extruder to prepare PP/TiO2 blends with different dispersant EBS content.The effects of dispersant EBS and compatibilizer PP-g-MAH on the dispersion and antibacterial effect of TiO2 in PP were compared.The results show that both EBS and PP-g-MAH can improve the compatibility between TiO2 and PP,resulting in enhanced mechanical and antibacterial properties of the PP/TiO2 blends.The small molecule EBS can enter the PP phase region,reducing the regularity of PP crystals and hindering the formation of lamellar crystal structures.PP-g-MAH,acting as a bridge,increases the compatibility between TiO2 and PP,inducing early crystallization of PP,leading to a better crystalline structure and higher antibacterial activity of the PP/TiO2 blends.关键词
二氧化钛/马来酸酐接枝聚丙烯/N,N'-乙撑双硬脂酰胺/相容性/抗菌活性Key words
TiO2/PP-g-MAH/EBS/Compatibility/Antibacterial activity分类
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郭月圆,宋立新,邵文君,张雨,刘欣,刘立志,史颖..EBS和PP-g-MAH对聚丙烯/纳米二氧化钛共混物性能的影响[J].塑料科技,2023,51(12):11-16,6.