纤维素加氢制取小分子醇的研究进展OACSTPCD
Research progress on the production of small molecule alcohols through hydrogenation of cellulose
纤维素是自然界储量最为丰富的生物质资源,纤维素催化加氢可得到山梨醇、甘露醇和1,2-戊二醇等小分子醇.笔者总结了纤维素加氢制备小分子醇的2种反应机制,详细综述了贵金属、过渡金属及金属和杂多酸类催化剂在纤维素加氢制取小分子醇中的研究进展,并且展望了该技术面临的挑战和未来发展方向.
Cellulose,the most abundant biomass resource in nature,can be subjected to catalytic hydrogenation to afford small molecule alcohols,suchsorbitol,mannitol,1,2-pentanediol,etc.Herein,we summarized the two types of reaction mechanisms for cellulose hydrogenation,and reviewed the research progress of various catalysts for such transformation,including precious metal catalysts,transition metal catalysts and metal+heteropolyacid catalysts.Finally,we presented the challenges and development directions of this technology.
马艺鸣;杨运松;杨晓瑞;朱建良;梁金花
南京工业大学生物与制药工程学院,江苏南京 211800
纤维素催化水解催化加氢小分子醇
cellulosecatalytic hydrolysiscatalytic hydrogenationmolecule alcohol
《生物加工过程》 2024 (001)
50-57,88 / 9
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