低碳化学与化工2024，Vol.49Issue(1)：42-51,10.DOI:10.12434/j.issn.2097-2547.20230152
DMO经两种反应路径加氢制乙醇催化剂研究进展
Research progress on catalysts for dimethyl oxalate hydrogenation to ethanol via two reaction pathways
摘要
Abstract
One significant route for producing ethanol(EtOH)indirectly from syngas is the hydrogenation of coal-based syngas to EtOH via dimethyl oxalate(DMO)intermediates.There are two reaction pathways for DMO hydrogenation to EtOH∶hydrogenation to EtOH via ethylene glycol(EG)intermediates and hydrogenation to EtOH via methyl acetate(MA)intermediates.The characteristics of two reaction pathways for DMO hydrogenation to EtOH were analyzed,and the catalysts commonly utilized in these pathways and the key factors affecting selectivity of EtOH were summarized.DMO hydrogenation to EtOH via EG intermediates typically requires high reaction temperature and synergistic catalysis of multiple active sites.The catalytic activity of commonly used Cu-based catalysts can be regulated from three aspects:support structure,preparation method and additive addition.The reaction temperature of DMO hydrogenation to EtOH via MA intermediates is relatively low,and commonly used catalysts are mainly transition metal carbides(Mo-base and Fe-base),but the hydrogenation capacity of catalysts is still insufficient.It helps to deepen the systematic understanding of the two pathways for DMO hydrogenation to EtOH and provides reference for the rational design and preparation of highly stable and low-cost catalysts for DMO hydrogenation to EtOH in the future.关键词
草酸二甲酯/加氢/乙醇/反应路径/合成气/催化剂Key words
dimethyl oxalate/hydrogenation/ethanol/reaction pathways/syngas/catalysts分类
化学化工引用本文复制引用
靳珲青,石晓丹,靳刘艳,艾培培,王晓东,黄伟..DMO经两种反应路径加氢制乙醇催化剂研究进展[J].低碳化学与化工,2024,49(1):42-51,10.基金项目
国家自然科学基金青年科学基金(22008166) （22008166）
山西省面上青年基金(201901D211047) （201901D211047）
山西省高等学校科技创新项目(2019L0185). （2019L0185）
