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碳布生长二维Co-MOF材料电容性能OA

Capacitive Properties of Carbon Cloth Grown Two-dimensional Co-MOF Material

中文摘要英文摘要

以 2,6-萘二羧酸为配体,通过一步溶剂热法在碳布表面制备了二维Co-MOF纳米片,并探究反应温度和反应时间对材料形貌和电化学性能的影响,经过SEM和XPS表征以及电化学性能测试.结果表明:制备的Co-MOF纳米片形貌规整、分布均匀;当反应温度为 160℃、反应时间为 12 h的Co-MOF/CC的电化学性能最优;三电极测试体系中,当扫描速率为 10 mV/s时其面积比电容为211.7 mF/cm2,在 10 mA/cm2 电流密度下经过 2000 次循环后电容保持率为 82.3%.

Two-dimensional Co-MOF nanosheets were prepared on the surface of carbon cloth by the one-step solvothermal method using 2,6-naphthalene dicarboxylic acid as a ligand.The effects of reaction temperature and time on the morphology and electrochemical performance of the material are investigated.After SEM and XPS characterization and electrochemical performance test,the results show that the prepared Co-MOF nanosheets have regular morphology and uniform distribution.The electrochemical performance of Co-MOF/CC is optimal when the reaction temperature is 160℃and the reaction time is 12 hours.The area-specific capacitance is 211.7 mF/cm2 at a scan rate of 10 mV/s,and the capacitance retention rate is 82.3%after 2000 cycles at a current density of 10 mA/cm2 in the three-electrode testing system.

田欣雨;冯晓苗

南京邮电大学 材料科学与工程学院,省部共建有机电子与信息显示国家重点实验室,信息材料与纳米技术研究院,江苏 南京 210023

化学工程

钴金属-有机框架电容性能二维纳米片碳布

Co-MOFcapacitive performancetwo-dimensional nanosheetcarbon cloth

《广州化学》 2024 (001)

28-32 / 5

国家自然科学基金资助项目(62174087)

10.16560/j.cnki.gzhx.20240117

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