低碳化学与化工2024，Vol.49Issue(2)：35-48,14.DOI:10.12434/j.issn.2097-2547.20230103
乙酰丙酸加氢制备γ-戊内酯催化剂研究进展
Research progress of catalyst for levulinic acid hydrogenation to γ-valerolactone
摘要
Abstract
Catalytic conversion of carbon-neutral and renewable biomass into liquid fuel and fine chemicals is one of main solutions to achieve carbon peaking and carbon neutrality goals,and γ-valerolactone(GVL)can be used as a green solvent and can be synthesized into high-grade aviation fuel.Levulinic acid(LA),as an important biomass-derived platform chemical,can be catalytically hydrogenated into highly value-added GVL.Biomass composition was briefly introduced first,and then the research progress of LA hydrogenation to GVL was fully reviewed based on the perspective of homogeneous and heterogeneous catalysts(Ru,Pd,Ni,Cu and bimetal).The catalyst structural properties,reaction performance,stability,structure-performance correlation and reaction mechanism were discussed in detail.Finally,the major challenges were analysized,future prospects and development trend for LA hydrogenation to GVL were further prospected,which can provide a basis for designing high-activity and acid-resisting Ru-based catalysts with large-scale commercial applications.关键词
生物质/乙酰丙酸/加氢/γ-戊内酯/催化剂Key words
biomass/levulinic acid/hydrogenation/γ-valerolactone/catalyst分类
化学化工引用本文复制引用
高晓庆,郑洪岩,薛彦峰,王峰,牛宇岚..乙酰丙酸加氢制备γ-戊内酯催化剂研究进展[J].低碳化学与化工,2024,49(2):35-48,14.基金项目
国家自然科学基金青年基金(22202148) （22202148）
山西省基础研究计划青年项目(202203021212326) （202203021212326）
山西省高等学校科技创新项目(2022L527) （2022L527）
太原工业学院引进人才科研资助项目(2022KJ051,2022LJ030). （2022KJ051,2022LJ030）
