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天然气水蒸汽重整制氢的PROII模拟分析

李林 蹇守华 申莉 李振光 刘卓衢 王继峰 王雪峰 刘定坤

低碳化学与化工2024,Vol.49Issue(2):124-128,5.
低碳化学与化工2024,Vol.49Issue(2):124-128,5.DOI:10.12434/j.issn.2097-2547.20220375

天然气水蒸汽重整制氢的PROII模拟分析

PROII simulation analysis of hydrogen production from natural gas steam reforming

李林 1蹇守华 1申莉 1李振光 2刘卓衢 1王继峰 1王雪峰 1刘定坤1

作者信息

  • 1. 西南化工研究设计院有限公司 工业排放气综合利用国家重点实验室,国家碳一化学工程技术研究中心,四川 成都 610225
  • 2. 内蒙古庆华集团乌斯太能源化工有限公司,内蒙古 阿拉善 750336
  • 折叠

摘要

Abstract

Natural gas steam reforming,as one of the most important hydrogen production processes,requires a significant amount of natural gas consumption.By optimizing the reforming process,it is possible to effectively reduce natural gas consumption.Using the chemical simulation software PROII,the conversion and shift reaction processes in the hydrogen production process from natural gas steam reforming were simulated.The error of the simulated value and the measured value of residual methane dry basis content(amount-of-substance fraction)is less than 1.5%,indicating that the simulation model is reliable and effective.Sensitivity analysis of the operating parameters in the conversion and shift reaction processes was also conducted based on this simulation model.The results show that when the water-carbon ratio(mole ratio)is 3.0,the outlet temperature of the conversion furnace is 820℃,and the outlet pressure is 1.2 MPa,the methane conversion rate of natural gas is higher(about 87%),and the fuel consumption is lower(about 70 m3/h).This is the optimal reforming condition and can be used as important process control indicators for actual production process.

关键词

天然气蒸汽重整/氢气/模拟分析/水碳比/温度/压力

Key words

natural gas steam reforming/hydrogen/simulation analysis/water-carbon ratio/temperature/pressure

分类

化学化工

引用本文复制引用

李林,蹇守华,申莉,李振光,刘卓衢,王继峰,王雪峰,刘定坤..天然气水蒸汽重整制氢的PROII模拟分析[J].低碳化学与化工,2024,49(2):124-128,5.

低碳化学与化工

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