无机材料的"化学剪刀"结构编辑策略
Chemical Scissor-mediated Structural Editing of Inorganic Materials
摘要
Abstract
Inspired by gene scissor concept in biological genetic engineering,chemical scissors,as important research tools,play an important role in the study of structure editing and application of materials.We aim to review the research progress of chemical scissors in structural editing and applications of materials.First of all,we introduce the basic concept and mechanism.Chemical scissors strategy refers to a methodology for material editing through which the main crystal structure is preserved but targeted atoms or structural units are knocked out,replaced,repaired or reconstructed in order to realize special functionality.Subsequently,the specific applications of chemical scissors in materials structure editing are discussed in depth,including the methods and functional designs for precise structure modulation of materials by chemical shearing,modification,synthesis,as well as etching and intercalation.Finally,the future research direction of chemical scissors in the field of material structure editing is envisioned,including developing new chemical scissors that are more intelligent and efficient,exploring more innovative strategies for material structure editing,understanding the underlying chemical mechanism,and further expanding the applicability of chemical scissors.Overall,we summarize the research progress and potential of material structural editing,which provides important theoretical and experimental support for further exploring and developing the application of chemical scissors in the field of materials.关键词
化学剪刀/无机材料/结构编辑/专题评述Key words
chemical scissor/inorganic material/structural editing/perspective分类
通用工业技术引用本文复制引用
丁浩明,陈科,李勉,李友兵,柴之芳,黄庆..无机材料的"化学剪刀"结构编辑策略[J].无机材料学报,2024,39(2):115-128,14.基金项目
浙江省重点研发计划(2022C01236) （2022C01236）
国家自然科学基金(52202325,52172254) （52202325,52172254）
浙江省自然科学基金(LQ22E020008) （LQ22E020008）
宁波市自然科学基金(20221JCGY010746,2023J352) （20221JCGY010746,2023J352）
浙江省高层次人才特殊支持计划(2022R51007) （2022R51007）
中国科学院国际合作伙伴计划(174433KYSB20190019)Key R&D Projects of Zhejiang Province(2022C01236) （174433KYSB20190019）
National Natural Science Foundation of China(52202325,52172254) （52202325,52172254）
Natural Science Foundation of Zhejiang Province(LQ22E020008) （LQ22E020008）
Natural Science Foundation of Ningbo(20221JCGY010746,2023J352) （20221JCGY010746,2023J352）
High-Level Talents Special Support Programme of Zhejiang Province(2022R51007) （2022R51007）
International Partnership Program of Chinese Academy of Sciences(174433KYSB20190019) （174433KYSB20190019）
