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SiO2-CIP/PDMS超疏水防除冰涂层的制备及性能研究OA

Preparation and Performance Study on SiO2-CIP/PDMS Superhydrophobic Anti-icing/Deicing Coating

中文摘要英文摘要

结冰是生活中一种常见的自然现象,但当冰层在基础设施或者交通工具等表面积聚时,会不可避免地影响它们的安全运行,进而带来设备失效的风险,甚至产生安全事故.因此,研究材料表面的防除冰机制,制备具有防除冰性能的功能性涂层材料,防止设备表面结冰,有助于提高各种设备的使用可靠性,具有重要的现实意义.受大自然中荷叶超疏水性能的启发,本文从提高材料表面疏水性的角度出发,结合羰基铁粉(CIP)深色金属粒子的太阳光响应性,以聚二甲基硅氧烷(PDMS)为基底,通过向其中引入定向CIP,然后再在其表面修饰SiO2纳米粒子,最终得到具有微纳结构的SiO2-CIP/PDMS超疏水防除冰涂层.结果表明,涂层的静态接触角高达159.7°±2°,滚动角低至2.7°±1°,其延迟结冰时间长达1120s,冰的黏附强度低至78.33kPa.本文所制备的涂层具有优异的超疏水、自清洁和防除冰性能,且具有一定的太阳光响应性,具有良好的户外防除冰应用前景.

Icing is a common natural phenomenon in life,but when ice accumulates on surfaces such as infrastructure or vehicles,it will inevitably affect their safe operation,resulting in the risk of equipment failure,and even safety accidents.Therefore,it is of great practical significance to study the anti-icing/deicing mechanism on the surface of materials and prepare functional coating materials with anti-icing/deicing properties to prevent icing on the surface of equipment,which helps to improve the reliability of various equipment.Inspired by the super hydrophobic properties of lotus leaves in nature,this paper combined with the sunlight responsiveness of Carbonyl Iron Powder(CIP)dark metal particles from the perspective of improving the surface hydrophobicity of materials,took PDMS as the substrate,introduced CIP into it,and then modified the surface of SiO2 nanoparticle,finally obtained SiO2-CIP/PDMS super hydrophobic anti-icing/deicing coating.The results show that the static contact angle of the coating is as high as 159.7°±2°,the rolling angle is as low as 2.7°±1°,the icing delay time is as long as 1120s,and the ice adhesion strength is as low as 78.33kPa.In summary,the coatings prepared in this paper have excellent superhydrophobic,self-cleaning and excellent anti-icing/deicing properties,and have certain sunlight response,which has good prospects for outdoor anti-icing/deicing applications.

刘宜松;张靖;苏芳芳;刘晨;郑亚萍

西北工业大学,陕西 西安 710072

防除冰超疏水微纳结构冰的黏附强度结冰延迟时间

anti icing/deicingsuperhydrophobicmicro nano structureadhesion strength of icefreezing delay time

《航空科学技术》 2024 (003)

20-27 / 8

航空科学基金(2018ZF053065) Aeronautical Science Foundation of China(2018ZF053065)

10.19452/j.issn1007-5453.2024.03.003

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