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非离子及两性型碳氢表面活性剂对全氟辛酸在土壤中迁移的影响

张庆泉 赵燕鹏 蔡兴 张琦 郭红岩 孙媛媛

南京大学学报(自然科学版)2024,Vol.60Issue(1):141-150,10.
南京大学学报(自然科学版)2024,Vol.60Issue(1):141-150,10.DOI:10.13232/j.cnki.jnju.2024.01.014

非离子及两性型碳氢表面活性剂对全氟辛酸在土壤中迁移的影响

Effects of nonionic and amphiphilic hydrocarbon surfactants on the transport of perfluorooctanoic acid in soils

张庆泉 1赵燕鹏 2蔡兴 2张琦 3郭红岩 4孙媛媛5

作者信息

  • 1. 江苏环保产业技术研究院股份公司,南京,210019||南京大学环境学院,南京,210023
  • 2. 江苏环保产业技术研究院股份公司,南京,210019
  • 3. 南京市浦口区水务局,南京,211800||南京大学地球科学与工程学院,南京,210023
  • 4. 南京大学环境学院,南京,210023
  • 5. 南京大学地球科学与工程学院,南京,210023
  • 折叠

摘要

Abstract

The extensive use of perfluorooctanoic acid(PFOA)leads to its widespread coexistence with kinds of hydrocarbon surfactants in the subsurface environment,which has posed potential risks to human health and ecological security.In this study,column experiments were conducted to explore the effect of nonionic hydrocarbon surfactant alkyl polyglycoside(APG)and amphiphilic surfactant dodecyl dimethyl betaine(BS-12)on the transport of PFOA in two saturated soils under different ionic strength.The results showed that APG could promote the transport of PFOA due to its competitive adsorption with PFOA on the soil surface.BS-12 could inhibit the transport of PFOA by neturalizing the negative charge on soil surface and hydrophobic interaction.Therefore,the effects coexisting hydrocarbon surfactants should be considered when predicting and evaluating the transport behavior of PFOA in soils.

关键词

全氟辛酸/非离子表面活性剂/两性表面活性剂/土壤性质

Key words

perfluorooctanoic acid/nonionic surfactant/amphiphilic surfactant/soil properties

分类

资源环境

引用本文复制引用

张庆泉,赵燕鹏,蔡兴,张琦,郭红岩,孙媛媛..非离子及两性型碳氢表面活性剂对全氟辛酸在土壤中迁移的影响[J].南京大学学报(自然科学版),2024,60(1):141-150,10.

基金项目

国家自然科学基金(42077109) (42077109)

南京大学学报(自然科学版)

OA北大核心CSTPCD

0469-5097

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