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阴阳离子组合捕收剂对微细粒赤铁矿与石英浮选分离的研究

贾蕗繁 罗溪梅 王云帆 宋振国 周永锋 蒋旺强 洪欣

矿产保护与利用2024,Vol.44Issue(1):33-39,7.
矿产保护与利用2024,Vol.44Issue(1):33-39,7.DOI:10.13779/j.cnki.issn1001-0076.2024.01.004

阴阳离子组合捕收剂对微细粒赤铁矿与石英浮选分离的研究

Research on the Flotation Separation of Fine-grained Hematite and Quartz by Combined Cation-anion Collectors

贾蕗繁 1罗溪梅 2王云帆 3宋振国 4周永锋 1蒋旺强 2洪欣1

作者信息

  • 1. 昆明理工大学 国土资源工程学院,云南 昆明 650093
  • 2. 昆明理工大学 国土资源工程学院,云南 昆明 650093||省部共建复杂有色金属资源清洁利用国家重点实验室,云南 昆明 650093
  • 3. 省部共建复杂有色金属资源清洁利用国家重点实验室,云南 昆明 650093||昆明理工大学 冶金与能源工程学院,云南 昆明 650093
  • 4. 矿物加工科学与技术国家重点实验室,北京 100160
  • 折叠

摘要

Abstract

The influence of four anionic collectors,namely sodium dodecyl sulfate(SDS),sodium lauryl sulfate(SLS),sodium dodecyl benzene sulfonate(SDBS),and sodium oleate(NaOL),in combination with the cationic collector dodecylamine(DDA),on the flotation separation of fine-grained(-18 μm)hematite and quartz was investigated.Single mineral experiments indicated that each of the four anionic collectors in combination with DDA reduced the flotation recovery of hematite in the foam product compared to DDA alone,thus favoring a reduction in the depressant dosage for hematite.When DDA was combined with anionic collectors,the order of separation effectiveness for fine-grained hematite and quartz was SDS>NaOL>SLS/SDBS.Among them,the DDA+SDS combinated collectors exhibited the best performance under certain mass ratio conditions.Under the optimal flotation conditions(pH=7,collector dosage of 20 mg/L,m(DDA)∶m(SDS)=2∶1,depressant dosage of 20 mg/L),the quartz recovery in the foam product reached 91.05%,while the hematite recovery was only 6.7%,facilitating hematite reverse flotation.Artificial mixed mineral flotation experiments showed that the DDA+SDS combinated collectors(m(DDA)∶m(SDS)=2∶1)achieved a concentrate with Fe grade of 45.7%and a recovery rate of 87.0%.Compared to DDA alone,this represented an increase of 1.7 and 18.6 percentage points,respectively,contributing to an improved separation efficiency of hematite and quartz.DDA+SDS can be considered an excellent anionic-cationic collectors for the flotation separation of fine-grained hematite and quartz.

关键词

赤铁矿/石英/十二胺/阴阳离子组合捕收剂/浮选

Key words

hematite/quartz/dodecylamine/combined cation-anion collector/flotation

分类

矿业与冶金

引用本文复制引用

贾蕗繁,罗溪梅,王云帆,宋振国,周永锋,蒋旺强,洪欣..阴阳离子组合捕收剂对微细粒赤铁矿与石英浮选分离的研究[J].矿产保护与利用,2024,44(1):33-39,7.

基金项目

国家自然科学基金项目(52364029 ()

52264030) ()

矿物加工科学与技术国家重点实验室开放基金资助项目(BGRIMM-KJSKL-2023-10) (BGRIMM-KJSKL-2023-10)

云南省科技厅昆明理工大学"双一流"创建联合专项面上项目(202201BE070001-048) (202201BE070001-048)

矿产保护与利用

OACSTPCD

1001-0076

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