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气溶胶化丁基黄药强化黄铁矿浮选回收机理研究

张帅 王宇斌 雷大士 吴忠意 张钰

矿产保护与利用2024,Vol.44Issue(1):53-60,8.
矿产保护与利用2024,Vol.44Issue(1):53-60,8.DOI:10.13779/j.cnki.issn1001-0076.2024.01.007

气溶胶化丁基黄药强化黄铁矿浮选回收机理研究

Flotation Mechanism of Pyrite Enhanced by Aerosolized Butyl Xanthate

张帅 1王宇斌 1雷大士 1吴忠意 1张钰1

作者信息

  • 1. 西安建筑科技大学 资源工程学院,陕西 西安 710055
  • 折叠

摘要

Abstract

In order to study the influence and mechanism of aerosol treatment of butyl xanthate on the flotation effect of pyrite,the single mineral flotation experiment of pyrite was carried out with aerosolized butyl xanthate as collector.The pyrite treated by butyl xanthate before and after aerosol treatment was characterized by conductivity,infrared spectroscopy and XPS.The results showed that the aerosolized butyl xanthate could significantly increase the content of the active ingredient dixanthogen in butyl xanthate and the flotation effect of pyrite.The recovery of pyrite was 57.20%at the mass concentration of butyl xanthate of 15 mg/L,which could increase the recovery of pyrite by 16.47 percentage points compared with that of untreated.Aerosolization treatment of butyl xanthate can increase the dissolved oxygen concentration in the butyl xanthate solution.Dissolved oxygen not only promote,the formation of dixanthogen in the solution,but also enhanced the collection effect of butyl xanthate on pyrite.It also affected the degree of oxidation reaction of pyrite,and the proportion of hydrophobic elemental sulfur increased 7.61%,which was beneficial to improve the floatability of pyrite.In addition,due to the increase of the adsorption amount of aerosolized butyl xanthate on the surface of pyrite,the hydrophobic group-C4H9 on the surface of pyrite increased,which improved the hydrophobicity of pyrite.The research provides a reference for aerosol flotation technology in the field of flotation.

关键词

气溶胶化/丁基黄药/强化/黄铁矿/浮选

Key words

aerosolization/butyl xanthate/strengthening/pyrite/flotation

分类

矿业与冶金

引用本文复制引用

张帅,王宇斌,雷大士,吴忠意,张钰..气溶胶化丁基黄药强化黄铁矿浮选回收机理研究[J].矿产保护与利用,2024,44(1):53-60,8.

基金项目

国家自然科学基金青年项目(52304192) (52304192)

中国博士后科学基金项目(2022MD723813) (2022MD723813)

矿产保护与利用

OACSTPCD

1001-0076

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