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某高钙钨尾矿反—正浮选工艺回收铷的研究

冯章标 阳华玲 王长福

矿产保护与利用2024,Vol.44Issue(1):89-94,6.
矿产保护与利用2024,Vol.44Issue(1):89-94,6.DOI:10.13779/j.cnki.issn1001-0076.2024.01.012

某高钙钨尾矿反—正浮选工艺回收铷的研究

Recovery of Rubidium from a Tungsten Tailings Containing High Calcite by Reverse-positive Flotation Process

冯章标 1阳华玲 1王长福1

作者信息

  • 1. 长沙矿冶研究院有限责任公司,湖南 长沙 410012
  • 折叠

摘要

Abstract

A tungsten tailings contains 0.098%rubidium,and the gangue minerals are mainly quartz,garnet,fluorite,and calcite.Rubidium is mainly present in muscovite,biotite,and potassium feldspar,and its distribution relationship with the gangue minerals is extremely complex,belonging to the associated high calcium low grade rubidium ore.In order to determine the rubidium recovery process,a reverse flotation decalcification rubidium flotation principle process was adopted.Detailed experiments were conducted on the collector,inhibitor,and selection process of reverse flotation decalcification coarse selection,as well as conditions such as rubidium flotation coarse selection activator,pulp pH,dodecylamine,and selected sodium hexametaphosphate.The results determined that a collector CYP+inhibitor SN-1 reagent system was used for reverse flotation decalcification,and a sulfuric acid+dodecylamine reagent system was used for rubidium positive flotation.Finally,through the closed circuit process of reverse flotation decalcification(two coarse and three fine)-fluorine-free low acid rubidium flotation(one coarse and one sweep and one fine),the Rb2O grade of rubidium concentrate was 0.214%,and the Rb2O recovery rate was 71.04%,effectively achieving the recovery of rubidium resources.

关键词

铷矿/云母/长石/反浮选/脱钙/无氟少酸

Key words

rubidium ore/mica/feldspar/reverse flotation/decalcification/hydrofluoric acid-free and less sulfuric acid

分类

矿业与冶金

引用本文复制引用

冯章标,阳华玲,王长福..某高钙钨尾矿反—正浮选工艺回收铷的研究[J].矿产保护与利用,2024,44(1):89-94,6.

矿产保护与利用

OACSTPCD

1001-0076

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