燃料化学学报（中英文）2024，Vol.52Issue(4)：496-511,16.DOI:10.1016/S1872-5813(23)60404-9
CO2催化制备高附加值多碳含氧化合物的研究进展
Research progress on CO2 catalytic conversion to value-added oxygenates
摘要
Abstract
Chemical conversion of greenhouse gas CO2 into value-added oxygenates such as ethanol,acetic acid,propanal,propionic acid,butanol,etc.is challenging due to the complexity of C-C coupling and the uncontrollable bonding.In this review,recent research progresses on the synthesis of multi-carbon oxygenates from CO2 in fixed bed reactor are provided.Firstly,the reaction mechanisms of CO2 hydrogenation are summarized.Then,the potential catalysts applied in one-step or tandem CO2 hydrogenation,dry reforming with light hydrocarbons and hydroformylation were introduced over metal carbides,alkali metal modified single or binary metal catalysts such as Cu,Fe,Co,Rh,etc.The reaction mechanism over different catalysts were further elaborated.Finally,the problems and outlook are discussed.关键词
二氧化碳转化/多碳含氧化合物/一步法/串联催化Key words
CO2 conversion/multi-carbon oxygenates/one-step method/tandem catalysis分类
化学化工引用本文复制引用
李永恒,吴冲冲,王文波,辛靖,米晓彤,杨国明,苏梦军,张斯然,李洪宝..CO2催化制备高附加值多碳含氧化合物的研究进展[J].燃料化学学报（中英文）,2024,52(4):496-511,16.基金项目
The project was supported by CNOOC Science and Technology Projects(KJGG-2022-12-CCUS-030401,030402).中国海洋石油集团有限公司科技项目(KJGG-2022-12-CCUS-030401,030402)资助 （KJGG-2022-12-CCUS-030401,030402）
