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三种β-取代茚三酮的合成及显现汗潜手印的研究

张岩峰 郭先超 马荣梁 孙振文 耿松 王铭兆

刑事技术2024,Vol.49Issue(2):128-134,7.
刑事技术2024,Vol.49Issue(2):128-134,7.DOI:10.16467/j.1008-3650.2023.0051

三种β-取代茚三酮的合成及显现汗潜手印的研究

Three β-substituted Ninhydrin Derivatives:Synthesis and Study on the Development of Latent Fingerprints

张岩峰 1郭先超 2马荣梁 3孙振文 3耿松 1王铭兆4

作者信息

  • 1. 四川警察学院刑事技术系,智能警务四川省重点实验室,四川泸州 646000
  • 2. 四川省成都市金堂县公安局,成都 610499
  • 3. 公安部鉴定中心,痕迹科学与技术公安部重点实验室,北京 100038
  • 4. 公安部刑事侦查局刑事技术处,北京 100741
  • 折叠

摘要

Abstract

The synthesis of three β-substituted ninhydrin derivatives and their application to the development of latent fingerprints on paper surfaces were investigated.Under the same concentration,the effects of β-OMe,β-NO2,β-Me ninhydrin were compared through latent fingerprint developments on different papers with multiple dimensions,respectively,and their effects were also compared with ninhydrin to analyze the advantages and disadvantages.Three β-substituted ninhydrin derivatives could develop fingerprints on different papers.The effect of β-NO2 ninhydrin was slightly inferior to the others as its solution was brown at the same time the displayed fingerprint was dark brown;the effect of β-OMe,β-Me ninhydrin was equivalent to ninhydrin in many dimensions and the sensitivity was slightly higher than ninhydrin,as well as the stability of Ruhemann's purple.The modification on β-position could change the fingerprint development effect of ninhydrin;the substitution of electron-donating groups could improve the fingerprint development effect of ninhydrin;the fluorescence performance of these compounds was not directly related to the visual effect of fingerprint display.

关键词

手印显现/渗透/半渗透客体/β-取代茚三酮

Key words

latent fingerprint development/semi-porous and porous surface/β-substituted ninhydrin

分类

社会科学

引用本文复制引用

张岩峰,郭先超,马荣梁,孙振文,耿松,王铭兆..三种β-取代茚三酮的合成及显现汗潜手印的研究[J].刑事技术,2024,49(2):128-134,7.

基金项目

痕迹科学与技术公安部重点实验室开放课题(2020FMKFKT03) (2020FMKFKT03)

刑事检验四川省高校重点实验室开放课题(2021YB03) (2021YB03)

智能警务四川省重点实验室资助项目(ZNJW2023ZZMS003) (ZNJW2023ZZMS003)

刑事技术

OACSTPCD

1008-3650

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