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硅基聚合物耐高温衍生陶瓷涂层制备与应用研究进展

陈科吉 李鹏飞 徐彩虹 吴子剑 张宗波

材料工程2024,Vol.52Issue(4):12-23,12.
材料工程2024,Vol.52Issue(4):12-23,12.DOI:10.11868/j.issn.1001-4381.2023.000560

硅基聚合物耐高温衍生陶瓷涂层制备与应用研究进展

Research progress in preparation and application of silicon-containing polymer derived high temperature resistant ceramic coatings

陈科吉 1李鹏飞 2徐彩虹 2吴子剑 3张宗波2

作者信息

  • 1. 哈尔滨理工大学 材料科学与化学工程学院,哈尔滨 150000||中国科学院化学研究所,北京 100190
  • 2. 中国科学院化学研究所,北京 100190
  • 3. 哈尔滨理工大学 材料科学与化学工程学院,哈尔滨 150000
  • 折叠

摘要

Abstract

With the continuous development of the aerospace field,the service conditions of high temperature structural components such as metal and carbon materials are increasingly harsh.The service life of high temperature structural components can be effectively improved by preparing silicon-based ceramic coatings on the surface of high temperature structural components and giving them special properties through appropriate processes.In recent years,the polymer precursors conversion ceramic coating has gradually become a novel method for preparing inorganic coatings.The new approach has the advantage of excellent processability and functional scalability,which gets more and more attention from researchers.The research progress of high temperature resistant ceramic coatings based on silicon-containing polymeric precursors was reviewed in this paper.Firstly,the preparation of ceramic coatings from the polymers was introduced,including the influences of silicon-based polymer precursors,fillers,coating and pyrolysis process on the structure and properties of the obtained coatings.Then,the applications of polymer-derived ceramic coatings in high temperature protection fields,such as anti-oxidation,environmental barrier and thermal barrier coatings were discussed.Finally,The problems in improving coating performance and defect control of polymer ceramic coatings were pointed out,and the development direction of polymer ceramic coatings was prospected,for example,by introducing ultra-high temperature elements such as Hf,Zr,Ta into silicon-based precursors,improving the temperature resistance level of ceramic coatings,and developing new efficient ceramic technology to improve the existing efficiency and applicability.

关键词

聚合物前驱体转化法/陶瓷涂层/高温防护/抗氧化/环境障/热障

Key words

polymer precursor-derived method/ceramic coating/high temperature protection/anti-oxida-tion/environmental barrier/thermal barrier

分类

化学

引用本文复制引用

陈科吉,李鹏飞,徐彩虹,吴子剑,张宗波..硅基聚合物耐高温衍生陶瓷涂层制备与应用研究进展[J].材料工程,2024,52(4):12-23,12.

基金项目

国防基础科研项目(JCKY2020203B019) (JCKY2020203B019)

材料工程

OA北大核心CSTPCD

1001-4381

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