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玻璃纤维滤材的疏水改性及过滤性能

陈欣 刘经国 张继荣 俞杰 李永国 李昕 林中鑫 裴鉴禄 郑芹 刘涛 张昭辰

材料工程2024,Vol.52Issue(4):200-208,9.
材料工程2024,Vol.52Issue(4):200-208,9.DOI:10.11868/j.issn.1001-4381.2023.000034

玻璃纤维滤材的疏水改性及过滤性能

Hydrophobic modification and filtration performance of glass fiber filter material

陈欣 1刘经国 1张继荣 1俞杰 1李永国 1李昕 1林中鑫 1裴鉴禄 1郑芹 1刘涛 1张昭辰1

作者信息

  • 1. 中国辐射防护研究院,太原 030006
  • 折叠

摘要

Abstract

The closed-cycle process will generate a large number of radioactive aerosols,and its high humidity,high acidity,and high radioactivity lead to rapid failure and high replacement frequency of glass fiber high-efficiency filters.In order to solve the above problems,hydrophobic modification of the traditional glass fiber filter material was proposed to improve its tolerance to severe conditions.The low surface energy modifier(polydimethylsiloxane)was used to realize the chemical hydrophobicity of filter material.The microstructure was constructed by introducing SiO2 nanoparticles to further improve hydrophobicity.The modification effect was analyzed by means of SEM,FTIR and contact angle measuring instrument,and the filtration performance of the modified filter material was further studied.The research results show that the modification can effectively improve the hydrophobicity of the glass fiber filter material and improve its moisture resistance.The static contact angle of the simply chemically modified filter material can reach 146°,and the modified filter material after the introduction of SiO2 nanoparticles exhibit an angle of more than 150°.When the mass fraction of polydimethylsiloxane and SiO2 nanoparticles is 2.0%and 0.5%,respectively,the corresponding filter material GF-PS-0.5 shows the best acid resistance,which is mainly due to the synergy of chemical hydrophobicity and microstructural hydrophobicity.The hydrophobicity of GF-PS-0.5 remains stable after a sufficient amount of γ-irradiation,indicating its good radiation resistance.The modified filter material maintains excellent filtration performance,and the filtration efficiency exceeds 99.99%.The modification process can improve the tolerance of the glass fiber filter material without influencing the filtration performance,showing a good application prospect.

关键词

闭式循环/玻璃纤维滤材/疏水改性/耐酸性/耐辐照性

Key words

closed-cycle process/glass fiber filter material/hydrophobic modification/acid resistance/radiation resistance

分类

化学化工

引用本文复制引用

陈欣,刘经国,张继荣,俞杰,李永国,李昕,林中鑫,裴鉴禄,郑芹,刘涛,张昭辰..玻璃纤维滤材的疏水改性及过滤性能[J].材料工程,2024,52(4):200-208,9.

基金项目

国家级科研项目(KY20007) (KY20007)

材料工程

OA北大核心CSTPCD

1001-4381

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