高等学校化学学报2024，Vol.45Issue(4)：137-142,6.DOI:10.7503/cjcu20240006
水相中烷基硫代酯的绿色合成
Green Synthesis of Alkyl Thioesters in Water
摘要
Abstract
A new,green and extra additive-free synthesis method of alkyl thioesters in water media was developed in this paper.By using alkyl halides and thioamide as the raw materials,the reaction can proceed smoothly in aqueous phase for 4 h,to afford the target thioester products with high yields,and the method can be compatible with various functional groups.Compared with the available methods,this method has the advantages of simple experimental operation,green and high efficiency,good atomic economy,and can easily be scaled up in gram scale,and has high practical application value.关键词
硫酯/卤代烃/硫代酰胺/水相Key words
Thioester/Alkyl halide/Thioamide/Water media分类
化学化工引用本文复制引用
闫晓雨,陈钰莹,赵媚,袁贻云,卞佳坤,马献涛..水相中烷基硫代酯的绿色合成[J].高等学校化学学报,2024,45(4):137-142,6.基金项目
国家自然科学基金(批准号:22101243)、河南省本科高校青年骨干教师培养计划(批准号:2023GGJS097)、信阳师范大学南湖学者青年项目和信阳师范大学研究生科研创新基金(批准号:2022KYJJ013)资助. Supported by the National Natural Science Foundation of China(No.22101243),the Young Backbone Teacher Training Objects of Colleges and Universities in Henan Province,China(No.2023GGJS097),the Nanhu Scholars Program for Young Scholars of Xinyang Normal University,China and the Graduate Research iInnovation Fund of Xinyang Normal University,China(No.2022KYJJ013). （批准号:22101243）
