化工进展2024，Vol.43Issue(3)：1252-1265,14.DOI:10.16085/j.issn.1000-6613.2023-0351
CO2与环氧化物耦合制备环状碳酸酯的多相催化体系研究进展
Research advance of heterogeneous catalytic system for the coupling between CO2 and epoxide into propylene carbonate
摘要
Abstract
As the most important greenhouse gas,carbon dioxide(CO2)has caused serious environmental problems by excessive emission.On the other hand,CO2 is an abundant,cheap,safe and renewable C1 resource,and thus is considered as an ideal carbon material in organic synthesis.Efficient and green chemical fixing CO2 to prepare cyclic carbonate with high boiling,high polarity,low volatility and biological degradability is an effective way of CO2 resource utilization,which has attracted wide attention.In this paper,the existing reaction pathways for the synthesis of cyclic carbonate are briefly described.Then,staring with the coupling reaction of CO2 with epoxides,we emphatically analyze the reaction mechanism,and the design ideas and current research advance of the heterogeneous catalytic system.Meanwhile,the advantages and disadvantages of the catalytic parameters such as catalytic conditions,catalytic activity and recyclability,of different heterogeneous catalytic systems are comprehensively compared.Finally,the application and development prospects of different heterogeneous catalytic systems are summarized and suggested.In the future,heterogeneous catalytic systems should be combined with homogeneous ones,which could efficiently activate CO2 and epoxides under mild conditions by utilizing their advantages.关键词
二氧化碳/催化剂/环氧化物/催化作用/耦合反应/环状碳酸酯Key words
carbon dioxide/catalyst/epoxides/catalysis/coupling reaction/cyclic carbonate分类
化学化工引用本文复制引用
刘方旺,韩艺,张佳佳,步红红,王兴鹏,于传峰,刘猛帅..CO2与环氧化物耦合制备环状碳酸酯的多相催化体系研究进展[J].化工进展,2024,43(3):1252-1265,14.基金项目
国家自然科学基金(22178191,82003647) （22178191,82003647）
潍坊职业学院博士基金. （）
