能源环境保护2024,Vol.38Issue(2):24-31,8.DOI:10.20078/j.eep.20240204
不同生物质原料催化制备5-羟甲基糠醛的研究进展
Progress in the catalytic conversion of 5-hydroxymethylfurfural prepared from different biomass feedstocks
摘要
Abstract
Biomass is widely recognized as a potentially abundant source of renewable energy,chemi-cals,materials,and more,making it an excellent alternative to traditional energy sources.5-hydroxy-methylfurfural(5-HMF),also known as HMF,is a versatile and critical renewable platform compound.It has earned the nickname"sleeping giant"due to its vast range of potential applications that can be derived from biomass-derived carbohydrates.Currently,saccharides serve as the primary raw materials for HMF preparation.In this paper,we delve into the mechanism of HMF synthesis and discuss the research progress on the catalytic preparation of 5-HMF from various feedstock sources,in-cluding hexoses,polysaccharides,and other biomasses.Previous studies indicate that the presence of metal elements can enhance the conversion rate of glucose,whereas for fructose,the focus lies more on designing a non-homogeneous catalyst to improve the yield.The hydrolysis of polysaccharides into mon-osaccharides is a crucial step for conversion,emphasizing both polysaccharide hydrolysis and monosac-charide conversion.Finally,we provide an outlook on the future research direction of HMF feedstocks,as well as the design and development of catalysts,aiming to offer theoretical support for future in-depth research.关键词
生物质/5-羟甲基糠醛/单糖/多糖Key words
Biomass/5-Hydroxymethylfurfural/Monosaccharides/Polysaccharides分类
资源环境引用本文复制引用
陶姣,潘云川,熊健,吕学斌..不同生物质原料催化制备5-羟甲基糠醛的研究进展[J].能源环境保护,2024,38(2):24-31,8.基金项目
科技部重点研发计划资助项目(2023YFC3902802) (2023YFC3902802)
国家自然科学基金资助项目(52066017) (52066017)
中央财政支持地方高校发展专项资金资助项目(2023年1号,2024年1号) (2023年1号,2024年1号)