能源环境保护2024,Vol.38Issue(2):81-93,13.DOI:10.20078/j.eep.20240311
电催化5-羟甲基糠醛氧化为2,5-呋喃二甲酸的研究进展
Research progress in electrooxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid
摘要
Abstract
With the increasing demand of alternative energy for achieving sustainable development,the effective utilization of biomass resources has become a research focus.5-Hydroxymethylfurfural(HMF),as a biomass-based platform compound,has broad application prospects.It can be converted into high value-added compounds such as 2,5-furandicarboxylic acid(FDCA)through selective oxi-dation.Electrooxidation,as a new green and environmentally friendly method,has made significant progress in the research of converting HMF to FDCA in recent years.However,this process involves competitive reactions,such as water oxidation,which affects the yield and Faradaic efficiency of FDCA.The catalyst is crucial for reducing reaction energy barriers and improving product selectivity,but it faces challenges such as insufficient stability,high overpotential,and insufficient activity in acid-ic environments.This review focuses on the research progress of high-performance catalysts,exploring in depth from noble metal catalysts to non-noble metal catalysts and non-metal catalysts,aiming to provide useful references for the efficient conversion of biomass.关键词
电化学氧化/生物质/5-羟甲基糠醛/2,5-呋喃二甲酸/电催化剂Key words
Electrooxidation/Biomass/5-Hydroxymethylfurfural/2,5-Furandicarboxylic acid/Elec-trocatalyst分类
资源环境引用本文复制引用
潘远江,郭珍燕,黄金术,李虎..电催化5-羟甲基糠醛氧化为2,5-呋喃二甲酸的研究进展[J].能源环境保护,2024,38(2):81-93,13.基金项目
国家自然科学基金资助项目(22368014) (22368014)