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焦油模型物与木屑共热解产物分布规律研究

李学琴 刘鹏 王玲玲 呼和涛力 王志伟 雷廷宙

能源环境保护2024,Vol.38Issue(2):136-144,9.
能源环境保护2024,Vol.38Issue(2):136-144,9.DOI:10.20078/j.eep.20231210

焦油模型物与木屑共热解产物分布规律研究

Study on the distribution law of co-pyrolysis products of tar models and sawdust

李学琴 1刘鹏 2王玲玲 2呼和涛力 2王志伟 3雷廷宙2

作者信息

  • 1. 常州大学城乡矿山研究院常州市生物质绿色安全高值利用技术重点实验室,江苏常州 213164||华东理工大学资源与环境工程学院能源化工系,上海 200237
  • 2. 常州大学城乡矿山研究院常州市生物质绿色安全高值利用技术重点实验室,江苏常州 213164
  • 3. 河南工业大学环境工程学院,河南郑州 450001||河南工业大学碳中和研究院,河南郑州 450001
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摘要

Abstract

In this study,toluene and acetic acid were investigated as model biomass tars,and sawdust was used as the feedstock.Co-pyrolysis experiments were conducted in a first-order fixed-bed reaction system to maximize the tar removal from sawdust.The distribution of co-pyrolysis products at different temperatures and the synergistic effects among the products were discussed.The results showed that compared to the pyrolysis of sawdust alone,the co-pyrolysis of sawdust with toluene and acetic acid ex-hibited a superior tar removal effect.Specifically,the co-pyrolysis of sawdust and toluene effectively reduced the tar yield by 81.47%.From the perspective of tar components,oxygen-containing com-pounds could not be effectively removed during the co-pyrolysis process,while aromatic hydrocarbons were easy to be removed by high-temperature co-pyrolysis.The synergistic effect of co-pyrolysis of acetic acid and sawdust was slightly weaker than that of toluene.The yield change of co-pyrolysis prod-ucts affected by temperature was consistent with that of sawdust pyrolysis alone.Furthermore,the inhib-itory effect of pyrolysis temperature on coke and tar was enhanced,providing a reference for tar removal and efficient conversion.

关键词

焦油模型物/木屑/共热解/热解温度/产物分布

Key words

Tar model/Sawdust/Co-pyrolysis/Pyrolysis temperature/Product distribution

分类

资源环境

引用本文复制引用

李学琴,刘鹏,王玲玲,呼和涛力,王志伟,雷廷宙..焦油模型物与木屑共热解产物分布规律研究[J].能源环境保护,2024,38(2):136-144,9.

基金项目

国家重点研发计划资助项目(2022YFB4201901) (2022YFB4201901)

江苏省碳达峰碳中和科技创新专项资金资助项目(BE2022426) (BE2022426)

能源环境保护

2097-4183

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