南京工业大学学报（自然科学版）2024，Vol.46Issue(2)：119-130,12.DOI:10.3969/j.issn.1671-7627.2024.02.001
金属羰基化合物参与催化反应的研究进展
Research progress for the metal-carbonyl-compound involved catalytic reactions
摘要
Abstract
Compounds with both electrophilic and nucleophilic centers have always been a key research interest in organic chemistry.As the most representative compound of this kind,M-homoenolate,functioning as a carbon nucleophilic reagent reacting with electrophilic reagent,facilitates the coupling reactions of carbon-carbon bonds and carbon-hetero bonds at β-position of carbonyl groups.The ubiquity of carbonyl functional groups in compounds including aldehydes,ketones,esters,and anhydrides underscores the scientific and market values of exploring M-homoenolate.Additionally,it is also an intermediate widely used in pharmaceutical chemistry and the synthesis of natural molecules.关键词
Homoenolate化学/金属羰基化合物/碳亲核试剂与亲电试剂Key words
homoenolate chemistry/metal-homoenolate/carbon electrophilic and carbon nucleophilic reagent分类
化学化工引用本文复制引用
林庭志,徐欣阳,沈旭涛,张东钊,徐云东,胡蔚然..金属羰基化合物参与催化反应的研究进展[J].南京工业大学学报（自然科学版）,2024,46(2):119-130,12.基金项目
江苏省自然科学基金青年基金(BK20220328) （BK20220328）
江苏省教育厅高校自然科学研究计划(22KJB150005) （22KJB150005）
中国博士后科学基金(2022M711596) （2022M711596）
江苏省卓越博士后计划(287706) （287706）
