南京工业大学学报（自然科学版）2024，Vol.46Issue(2)：149-159,11.DOI:10.3969/j.issn.1671-7627.2024.02.004
钪改性ZSM-5分子筛的制备及其在甲醇制烯烃反应中的催化性能
Preparation of Scandium modified ZSM-5 zeolite and its catalytic performance in methanol to olefin reaction
摘要
Abstract
Scandium(Sc)was successfully incorporated into the framework of ZSM-5 catalysts via an in-situ synthesis method,maintaining the original MFI-type topological structure of ZSM-5 zeolites.X-ray diffraction(XRD)analysis and scanning electron microscopy(SEM)of Sc-ZSM-5 revealed no significant changes in crystal structure,with no coexisting phases detected.SEM and nitrogen adsorption-desorption assays demonstrated that the accumulation of small crystals led to the formation of a pronounced micro-mesoporous composite hierarchical pore structure.Characterization utilizing X-ray photoelectron spectroscopy(XPS),energy-dispersive X-ray spectroscopy(EDS),and inductively coupled plasma atomic emission spectroscopy(ICP-AES)confirmed the successful integration of Sc atoms into the ZSM-5 catalyst framework.The ion-exchanged H-form Sc-ZSM-5 zeolite was employed in the methanol-to-olefins(MTO)reaction and compared with conventional ZSM-5 zeolites.Sc-ZSM-5 exhibited a marginally enhanced catalytic lifetime due to its more open pore structure.Furthermore,the introduction of Sc into the modified zeolite significantly improved the selectivity towards propylene and lower olefins by modulating the acidity and the spatial distribution of Al within the ZSM-5 framework.关键词
ZSM-5分子筛/Sc改性分子筛/多级孔结构/甲醇制烯烃/低碳烯烃Key words
ZSM-5 zeolite/scandium modified zeolite/multistage pore structure/methanol to olefin/low-carbon alkenes分类
化学化工引用本文复制引用
马奔,邓敦彬,吴梦菲,陈立宇,曲云龙,陆琨..钪改性ZSM-5分子筛的制备及其在甲醇制烯烃反应中的催化性能[J].南京工业大学学报（自然科学版）,2024,46(2):149-159,11.基金项目
国家自然科学基金(22202132) （22202132）
