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碳纳米管增强硬质合金的制备及性能研究

刘岩岩 张鹏 熊德树 张柯

有色金属材料与工程2024,Vol.45Issue(2):9-16,8.
有色金属材料与工程2024,Vol.45Issue(2):9-16,8.DOI:10.13258/j.cnki.nmme.20230308001

碳纳米管增强硬质合金的制备及性能研究

Preparation and properties of carbon nanotube-reinforced cemented carbide

刘岩岩 1张鹏 1熊德树 2张柯1

作者信息

  • 1. 上海理工大学 材料与化学学院,上海 200093
  • 2. 昆山长鹰硬质材料科技股份有限公司,昆山 215316
  • 折叠

摘要

Abstract

In order to reduce the agglomeration of reinforcing carbon nanotubes in cemented carbide,the surface of CNTs was modified by electroless nickel plating.CNTs reinforced WC-10Co cemented carbide as well as CNTs/Ni reinforced WC-10Co cemented carbide was prepared by gas pressure sintering process.The surface morphology,structure and composition of CNTs before and after Ni plating were characterized,and the effects of CNTs and CNTs/Ni on the structure and performance of cemented carbides.The results showed that the surface was covered with dense Ni nanoparticles after electroless plating,and the agglomeration of carbon nanotubes was significantly improved.With the addition of CNTs and CNTs/Ni,the grain of cemented carbide is effectively refined with less porosity.Compared to the unadded,the bending strength of the cemented carbide with the additive score of 0.1%CNTs and the cemented carbide with the additive score of 0.1%CNTs/Ni increased by 17.5%and 28.2%,and the thermal diffusivity increased by 23.5%and 40.8%,respectively.

关键词

碳纳米管/化学镀/硬质合金/抗弯强度/热扩散系数

Key words

carbon nanotubes/electroless plating/cemented carbide/bending strength/thermal diffusivity

分类

金属材料

引用本文复制引用

刘岩岩,张鹏,熊德树,张柯..碳纳米管增强硬质合金的制备及性能研究[J].有色金属材料与工程,2024,45(2):9-16,8.

基金项目

国家自然科学基金资助项目(No.51971148) (No.51971148)

有色金属材料与工程

2096-2983

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