CO2快速吞吐提高页岩油采收率现场试验OA北大核心CSTPCDEI
Field tests and effect of CO2 rapid huff-n-puff to enhance shale oil recovery
页岩油注CO2吞吐提高采收率技术处于探索阶段,目前面临着CO2与页岩储层及流体相互作用机制不明确、数值模拟技术不成熟、缺乏规模注采及低成本回收工艺等技术难题.为探索页岩油注CO2提高采收率主控机理,以苏北盆地溱潼凹陷古近系阜宁组二段页岩油为对象开展了超临界CO2水岩反应实验,分析了高温高压条件下页岩矿物溶蚀作用及其对孔隙度和渗透率的影响,并通过注CO2恒质膨胀实验、最小混相压力测试评价了地层超压条件下注CO2后原油高压物性变化特征,并在此基础上开展考虑多因素数值模拟研究优化了设计注入参数,最终通过矿场试验验证了技术可行性.研究结果表明:①CO2水岩反应以碳酸质矿物溶蚀占主导,长英质矿物部分溶解,生成中大孔隙;②在地层原油中注入适量的CO2,显著萃取了原油中间烃组分,原油黏度从5.151 mPa·s下降到1.250 mPa·s,且CO2首先萃取轻烃组分,随生产时间增加萃取组分逐渐变为重烃;③基于人工压裂与天然缝网混合介质组分数模模型,优化设计单井吞吐注气量1.7×104t,注气速度500~600 t/d,焖井时间50d;④低压侧加热的页岩油CO2吞吐地面工艺,可依据CO2注入地面工艺多参数数据模型,实现精准控温,避免注入管线冻堵及井下油管和套管材料低温脆断问题;⑤产出气CO2浓度高于80%时,采用气相回收直注工艺,实现产出气回收成本降至104元/t.结论认为,CO2快速吞吐有效提高了页岩油采收率,形成的机理认识和技术系列可为页岩油注CO2吞吐开发提供参考和借鉴.
The technology of CO2 huff-n-puff for enhancing shale oil recovery is still in an exploratory stage.There are some technical challenges,such as unclear mechanism of interaction between CO2 and shale reservoirs/fluids,immature numerical simulation techniques,and absence of large-scale injection-production and low-cost recovery processes.A shale oil well in the second section of the Funing Formation of the Paleogene in the Qintong Depression of the Subei Basin was taken as a case of study.To figure out the dominant mechanism of CO2 huff-n-puff for enhancing shale oil recovery,this paper conducts an experiment on water-rock reaction with supercritical CO2 to investigate the dissolution of shale minerals at high temperature and pressure and its impacts on porosity and permeability.Then,the constant-mass expansion(CME)and minimum miscibility pressure(MMP)tests with CO2 injection are carried out to evaluate the changes in physical properties of crude oil at high pressure after CO2 injection into overpressured reservoirs.On this basis,multi-factor numerical simulation is conducted to optimize the injection parameters.Finally,a CO2 thermodynamics and fluid dynamics data template is established to optimize the surface process.The proposed technology is verified through field tests.The results show that the water-rock reaction with CO2 is dominated by the dissolution of carbonate minerals,and partial dissolution of felsic minerals,forming medium and large pores.By injecting appropriate volume of CO2 into formation oil,the intermediate hydrocarbon components of the crude oil are extracted significantly,allowing the viscosity of crude oil to decrease from 5.151 mPa·s to 1.250 mPa·s.Moreover,CO2 first extracts the light hydrocarbon components,and then the heavy hydrocarbons with the production time.Based on the compositional numerical model of mixed media(artificial fractures and natural fractures),the parameters of huff and puff in a single well are optimized with the injection rate being 1.7×104t,the injection velocity being 500-600 t/d,and the soaking time being 50 days.The surface process of side heating at low pressure for CO2 huff and puff achieves an accurate temperature control with the support of the multi-parameter model of surface process for CO2 injection,so that the problems such as freezing/blocking of injection pipes and brittle failure of donwhole tubing and casing at low temperature can be avoided.When the concentration of CO2 in produced gas is greater than 80%,the gas phase recovery and direct injection process is adopted to reduce the cost of produced gas recovery to CNY104/t.It is concluded that the technology of CO2 rapid huff and puff effectively enhances the recovery of shale oil.The relevant understanding on mechanism and techniques can provide reference and guidance for shale oil development by huff-n-puff.
姚红生;高玉巧;郑永旺;邱伟生;龚月;钱洋慧
中国石化华东油气分公司
石油、天然气工程
页岩油注CO2水岩反应机理混合介质组分数模快速吞吐地面工艺现场试验
Shale oilCO2 injectionWater-rock reactionMechanismCompositional numerical modeling of mixed mediaRapid huff-n-puffSurface processField test
《天然气工业》 2024 (003)
10-19 / 10
江苏省重大科技示范项目"苏北地区二十万吨级CCUS重大科技示范工程"(编号:BE2022603)、中国石化科技部项目"苏北高陡构造带页岩油直井有效开发关键技术与示范"(编号:P23151)、中国石化科技部项目"苏北CCUS-EOR一体化技术研究"(编号:P21107).
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