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白云鄂博矿选冶固废烧结法制备微晶玻璃研究

翟飞龙 王艺慈 张云昊 吕智智 安胜利 柴轶凡 罗果萍

硅酸盐通报2024,Vol.43Issue(4):1284-1291,8.
硅酸盐通报2024,Vol.43Issue(4):1284-1291,8.

白云鄂博矿选冶固废烧结法制备微晶玻璃研究

Preparation of Glass-Ceramics by Sintering Selected Smelting Solid Waste of Bayan Obo Mine

翟飞龙 1王艺慈 1张云昊 1吕智智 1安胜利 1柴轶凡 1罗果萍1

作者信息

  • 1. 内蒙古科技大学轻稀土资源绿色提取与高效利用教育部重点实验室,包头 014010||内蒙古科技大学稀土产业学院,包头 014010
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摘要

Abstract

In order to make comprehensive use of solid waste from Bayan Obo Mine,the effects of different raw material ratios on the preparation of glass-ceramics were studied by one-step sintering method with fluorite tailings of Bayan Obo and blast-furnace slag of Baotou Steel as main raw materials.DSC,XRD,SEM,universal testing machine and multi-channelγ spectrometer were used to characterize and analyze the effects of different raw material ratios on the preparation of glass-ceramics.The results show that the main crystalline phases of glass-ceramics are clinopyroxene,diopside and tridymite when the ratio of raw materials is different.With the increase of the mass ratio of fluorite tailings to blast-furnace slag,the color of glass-ceramics gradually darkens,and the flexural strength increases first and then decreases,then increases and decreases.When the mass ratio of fluorite tailings to blast-furnace slag is 5∶5,the flexural strength of glass-ceramics is the highest,reaching 76.85 MPa,and the main crystalline phase is clinopyroxene and diopside,with uniform grain size and regular arrangement.When the mass ratio of fluorite tailings to blast furnace slag is 2∶8,the glass-ceramics product meet the class B decoration material standard,and when the mass ratio is 3∶7,5∶5,6∶4,it meets the class C decoration material standard.

关键词

微晶玻璃/白云鄂博矿/选冶固废/烧结法/放射性

Key words

glass-ceramics/Bayan Obo Mine/selected smelting soild waste/sinter process/radioactivity

分类

化学化工

引用本文复制引用

翟飞龙,王艺慈,张云昊,吕智智,安胜利,柴轶凡,罗果萍..白云鄂博矿选冶固废烧结法制备微晶玻璃研究[J].硅酸盐通报,2024,43(4):1284-1291,8.

基金项目

国家重点研发计划(2020YFC1909105) (2020YFC1909105)

内蒙古自治区科技重大专项计划(2021ZD0016) (2021ZD0016)

内蒙古科技成果转化专项项目(2019CG073) (2019CG073)

内蒙古自治区高等学校科学研究项目(NJZZ23056) (NJZZ23056)

内蒙古自治区直属高校基本科研业务费项目 ()

硅酸盐通报

OA北大核心CSTPCD

1001-1625

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