掺珊瑚砂粉砂浆抗硫酸镁侵蚀性能研究OA北大核心CSTPCD
Magnesium Sulfate Attack Resistance of Mortar with Coral Sand Powder
本文研究了硫酸镁作用下掺珊瑚砂粉(CSP)和辅助胶凝材料(SCMs)砂浆的抗硫酸镁侵蚀性能.在5和20 ℃硫酸镁溶液中侵蚀至365 d,通过外观、长度变化、抗压强度,结合X射线衍射谱和傅里叶变换红外光谱分析砂浆的抗硫酸镁侵蚀性能.发现在5 ℃的硫酸镁溶液中侵蚀至365 d时,掺CSP砂浆发生严重劣化.掺20%(质量分数)CSP的抗硫酸盐硅酸盐水泥比掺20%(质量分数)CSP的普通硅酸盐水泥表现出更好的抗硫酸镁侵蚀性能.在5℃下粉煤灰和矿渣有助于改善掺CSP砂浆的抗硫酸镁侵蚀性能,然而在20 ℃下硅灰降低其抗硫酸镁侵蚀性能.在5 ℃下掺CSP砂浆主要发生镁盐和碳硫硅钙石型硫酸盐侵蚀并伴随少量石膏生成,在20 ℃下主要发生镁盐和石膏型硫酸盐侵蚀.
This paper investigated the magnesium sulfate resistance of mortar incorporating coral sand powder(CSP)combined with supplementary cementitious materials(SCMs).With erosion in magnesium sulfate(MgSO4)solution at 5 and 20 ℃ for 365 d,the magnesium sulfate attack resistance of mortar was analyzed through appearance,length change,compressive strength,X-ray diffraction pattern and Fourier transform infrared spectroscopy.It is found that the mortar with CSP deteriorates seriously when it is eroded to 365 d in magnesium sulfate solution at 5 ℃.Sulfate resistantance Portland cement(SRPC)with 20%(mass fraction)CSP exhibits better magnesium sulfate attack resistance than ordinary Portland cement(OPC)with 20%(mass fraction)CSP.Fly ash and slag can effectively improve the magnesium sulfate attack resistance of mortar with CSP at 5 ℃,while silica fume reduces the magnesium sulfate attack resistance at 20 ℃.At 5 ℃,the mortar with CSP mainly undergos magnesium and thaumasite sulfate corrosion accompanied by a small amount of gypsum generation,while at 20 ℃,magnesium and gypsum-type sulfate corrosion mainly occurs.
马英;李淯伟;邰安
南京工业大学材料科学与工程学院,南京 211816
土木建筑
珊瑚砂粉硫酸镁侵蚀碳硫硅钙石粉煤灰矿渣硅灰
coral sand powdermagnesium sulfate attackthaumasitefly ashslagsilica fume
《硅酸盐通报》 2024 (004)
1380-1387 / 8
国家自然科学基金青年科学基金(51802151)
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