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氧化钪对钾长石结晶釉组织结构和性能的影响

杨家瑞 杜景红 黄涛 孟雪 陈家兴 秦朝乾 何胜阳

硅酸盐通报2024,Vol.43Issue(4):1506-1514,9.
硅酸盐通报2024,Vol.43Issue(4):1506-1514,9.

氧化钪对钾长石结晶釉组织结构和性能的影响

Effect of Scandium Oxide on Structure and Properties of Potassium Feldspar Crystalline Glaze

杨家瑞 1杜景红 1黄涛 2孟雪 2陈家兴 1秦朝乾 1何胜阳1

作者信息

  • 1. 昆明理工大学材料科学与工程学院,昆明 650093
  • 2. 辽宁爱尔创生物材料有限公司,本溪 117004
  • 折叠

摘要

Abstract

Glazes composed of potassium feldspar as main crystals hold promising potential for addressing the issues of insufficient bonding strength and high brittleness in tetragonal zirconia ceramics.The effect of scandium oxide content on structure and characteristics of potassium feldspar crystalline glazes was studied by DSC,XRD,SEM,hardness,strength,refractive index,visible light transmittance and thermal expansion tests.The results indicate that as Sc2O3 content increases from 0%(mass fraction,the same below)to 10%,the crystallization temperature of crystalline glaze decreases from 958.5℃ to 827.8℃,accompanied by an increase in crystallization capacity.Furthermore,the grain size of sintered crystalline glaze steadily enlarges.With the increase of Sc2O3 content,scandium silicate crystals precipitate within the crystalline glaze.The crystallinity,knoop hardness,bending strength and refractive index of crystalline glaze reach their optimal values at Sc2O3 content of 6.67%.The visible light transmittance decrease first and then increase,while the thermal expansion coefficient decreases.

关键词

结晶釉/钾长石/氧化钪/力学性能/热膨胀

Key words

crystalline glaze/potassium feldspar/Sc2O3/mechanical property/thermal expansion

分类

医药卫生

引用本文复制引用

杨家瑞,杜景红,黄涛,孟雪,陈家兴,秦朝乾,何胜阳..氧化钪对钾长石结晶釉组织结构和性能的影响[J].硅酸盐通报,2024,43(4):1506-1514,9.

基金项目

云南省科技人才与平台计划项目(202105AD160020) (202105AD160020)

硅酸盐通报

OA北大核心CSTPCD

1001-1625

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