日用化学工业(中英文)2024,Vol.54Issue(4):457-466,10.DOI:10.3969/j.issn.2097-2806.2024.04.012
驱油用表面活性剂及其吸附特性的研究进展
Recent advances of surfactants and their adsorption characteristics in oil recovery
摘要
Abstract
Enhanced oil recovery is an important guarantee for increasing energy production in China.Chemical flooding based on surfactants is an important method to enhance oil recovery.The classification of surfactants used in oil displacement were introduced.The physicochemical characteristics of surfactants and their advantages and disadvantages in oil displacement were also introduced in detail,including the widely used anionic,zwitterionic and nonionic surfactants and the rarely used Gemini surfactants.As the demand of oil industry is changing,synthesis of green surfactants with low cost and high efficiency has become the main trend of future development.During the process of oil displacement,the adsorption of surfactants will reduce the effective concentration of surfactants in solution,resulting in the significant decrease of oil displacement efficiency.Therefore,herein,the research progress of adsorption properties of surfactants used in oil displacement at solid-liquid interface was also reviewed.The adsorption isotherm models are mainly used to describe the relationship between the amount adsorbed at solid-liquid interface and the surfactant concentration after equilibrium at constant temperature.The adsorption kinetic models can be used to evaluate the relationship between adsorption rate and time,revealing the mechanism of adsorption.To describe the adsorption properties of surfactants more comprehensively and accurately,it is necessary to develop new adsorption models and use multiple models in combination.关键词
表面活性剂/提高原油采收率/吸附等温线/吸附动力学Key words
surfactant/enhanced oil recovery/adsorption isotherm/adsorption kinetics分类
能源科技引用本文复制引用
刘子龙,黑艳晓,石迪,肖宇飞,李雪..驱油用表面活性剂及其吸附特性的研究进展[J].日用化学工业(中英文),2024,54(4):457-466,10.基金项目
中国石油大学(北京)校级自主科研基金(No.2462020BJRC007 (北京)
No.2462022YXZZ007) ()
油气资源与工程全国重点实验室(No.PRE/DX-2408) (No.PRE/DX-2408)