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氢氧化镁形貌对环氧树脂阻燃性能的影响

郭凡 焦伟先 黄伦 孟喜 刘晨 叶丹阳 李丽娟

塑料科技2024,Vol.52Issue(3):99-105,7.
塑料科技2024,Vol.52Issue(3):99-105,7.DOI:10.15925/j.cnki.issn1005-3360.2024.03.020

氢氧化镁形貌对环氧树脂阻燃性能的影响

Effect of Magnesium Hydroxide Morphology on Flame Retardancy of Epoxy Resin

郭凡 1焦伟先 1黄伦 1孟喜 1刘晨 2叶丹阳 1李丽娟3

作者信息

  • 1. 湖北隆中实验室,湖北襄阳 441000||湖北航天化学技术研究所,湖北襄阳 441003
  • 2. 湖北航天化学技术研究所,湖北襄阳 441003
  • 3. 中国科学院青海盐湖研究所,青海西宁 810008
  • 折叠

摘要

Abstract

The morphology of the material has a great influence on its flame retardancy.In order to study the effects of magnesium hydroxide with different morphologies on the flame retardancy of epoxy resin,magnesium chloride and magnesium sulfate were used as raw materials to prepare magnesium hydroxide with rod,flake and flower,and were added to epoxy resin to prepare epoxy resin composite to explore the flame retardancy and the flame retardant mechanism.The results show that the diameter of rod magnesium hydroxide ranges from 250 nm to 500 nm and the length is about 5 μm.The flaky magnesium hydroxide has a hexagonal sheet structure with a size of 100 nm.The size of flower ball magnesium hydroxide is 1~2 μm.When the addition of magnesium hydroxide is 3%,the flame retardancy of epoxy resin is improved as:flake>flower>rod.Compared with pure epoxy resin,the addition of flaky magnesium hydroxide reduceds the TSP by 35.1%,the PHRR by 36.6%,and the PCOP by 39.4%.The research provides the direction for the application of magnesium hydroxide in polymers.

关键词

氢氧化镁形貌/环氧树脂/阻燃性能

Key words

Magnesium hydroxide morphology/Epoxy resin/Flame retardancy

分类

化学化工

引用本文复制引用

郭凡,焦伟先,黄伦,孟喜,刘晨,叶丹阳,李丽娟..氢氧化镁形貌对环氧树脂阻燃性能的影响[J].塑料科技,2024,52(3):99-105,7.

基金项目

湖北省自然科学基金-襄阳创新发展联合基金(2022CFD088) (2022CFD088)

塑料科技

OA北大核心CSTPCD

1005-3360

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